A practical innovative method for highly selective oxidation of alcohols in neat water using water-insoluble iron and manganese porphyrins as reusable heterogeneous catalysts

被引：34
|
作者：
Rezaeifard, Abdolreza [1 ]
Jafarpour, Maasoumeh [1 ]
Naeimi, Atena [1 ]
机构：
[1] Univ Birjand, Fac Sci, Dept Chem, Catalysis Res Lab, Birjand 97179414, Iran
来源：
CATALYSIS COMMUNICATIONS | 2011年 / 16卷 / 01期
关键词：
Porphyrin; Oxidation; Alcohol; Water; Heterogeneous catalyst; TETRABUTYLAMMONIUM PEROXYMONOSULFATE; MESO-TETRAPHENYLPORPHYRIN; ORGANIC-REACTIONS; EFFICIENT;
D O I：
10.1016/j.catcom.2011.09.039
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A novel heterogeneous method for clean and selective oxidation of alcohols to the aldehydes and ketones using tetrabutylammonium peroxomonosulfate (n-Bu4NHSO5) in neat water catalyzed by simple Fe (III) and Mn (III) meso-tetraphenylporphyrin as a water-insoluble catalyst has been developed. The oxidation system proceeds well in the absence of organic co-solvents and surfactants. The presence of an electron-donating group on the phenyl ring of benzyl alcohol increases the reactivity of substrate. The catalysts could easily be recycled and reused without noticeable loss of activity and the oxidant's by-product (n-Bu4NHSO4) could also be recycled. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码：240 / 244
页数：5
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