Dehydrogenative Oxidation of Alcohols in Aqueous Media Using Water-Soluble and Reusable Cp*Ir Catalysts Bearing a Functional Bipyridine Ligand

被引：354
|
作者：
Kawahara, Ryoko [1 ]
Fujita, Ken-ichi [1 ,2 ]
Yamaguchi, Ryohei [1 ]
机构：
[1] Kyoto Univ, Grad Sch Human & Environm Studies, Sakyo Ku, Kyoto 6068501, Japan
[2] Kyoto Univ, Grad Sch Global Environm Studies, Sakyo Ku, Kyoto 6068501, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 08期
关键词：
OPPENAUER-TYPE OXIDATION; EFFICIENT HYDROGEN-PRODUCTION; OXIDANT-FREE OXIDATION; SECONDARY ALCOHOLS; RUTHENIUM COMPLEXES; ORGANIC-REACTIONS; ACCEPTORLESS DEHYDROGENATION; HOMOGENEOUS RUTHENIUM; IRIDIUM COMPLEX; ALDEHYDES;
D O I：
10.1021/ja210857z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new catalytic system for the dehydrogenative oxidation of alcohols using a water-soluble Cp*Ir complex bearing a bipyridine-based functional ligand as catalyst has been developed. With this catalytic system, a variety of primary and secondary alcohols have been efficiently converted to aldehydes and ketones, respectively, in aqueous media without using any oxidant. Reuse of the catalyst by a very simple procedure has been also accomplished.
引用
收藏
页码：3643 / 3646
页数：4
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