Dehydrogenative Oxidation of Alcohols in Aqueous Media Using Water-Soluble and Reusable Cp*Ir Catalysts Bearing a Functional Bipyridine Ligand

被引：354

作者：

Kawahara, Ryoko ^{[1
]}

Fujita, Ken-ichi ^{[1
,2
]}

Yamaguchi, Ryohei ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Human & Environm Studies, Sakyo Ku, Kyoto 6068501, Japan

[2] Kyoto Univ, Grad Sch Global Environm Studies, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2012年 / 134卷 / 08期

关键词：

OPPENAUER-TYPE OXIDATION; EFFICIENT HYDROGEN-PRODUCTION; OXIDANT-FREE OXIDATION; SECONDARY ALCOHOLS; RUTHENIUM COMPLEXES; ORGANIC-REACTIONS; ACCEPTORLESS DEHYDROGENATION; HOMOGENEOUS RUTHENIUM; IRIDIUM COMPLEX; ALDEHYDES;

D O I：

10.1021/ja210857z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new catalytic system for the dehydrogenative oxidation of alcohols using a water-soluble Cp*Ir complex bearing a bipyridine-based functional ligand as catalyst has been developed. With this catalytic system, a variety of primary and secondary alcohols have been efficiently converted to aldehydes and ketones, respectively, in aqueous media without using any oxidant. Reuse of the catalyst by a very simple procedure has been also accomplished.

引用

页码：3643 / 3646

页数：4

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