A novel strategy for clean and selective oxygenation of hydrocarbons with n-Bu4NHSO5 in neat water catalyzed by recyclable water-insoluble iron (III) tetraphenylporphyrins

被引：24

作者：

Rezaeifard, Abdolreza ^{[1
]}

Jafarpour, Maasoumeh ^{[1
]}

Naeimi, Atena ^{[1
]}

Kaafi, Samira ^{[1
]}

机构：

[1] Univ Birjand, Fac Sci, Dept Chem, Catalysis Res Lab, Birjand 97179414, Iran

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 12卷 / 08期

关键词：

Porphyrin; Peroxomonosulfate; Oxygenation; Hydrocarbons; Water; MANGANESE MESO-TETRAPHENYLPORPHYRIN; TETRABUTYLAMMONIUM PEROXYMONOSULFATE; ORGANIC-REACTIONS; OXIDATION; EPOXIDATION; EFFICIENT; ALCOHOLS; DERIVATIVES; ALKENES;

D O I：

10.1016/j.catcom.2011.01.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel heterogeneous method for efficient oxygenation of olefins to epoxides and saturated hydrocarbons to the related ketones using tetrabutylammonium peroxomonosulfate (n-Bu4NHSO5) in neat water catalyzed by Fe(TPP)Cl and Fe(TDCPP)Cl complexes as water-insoluble catalysts has been developed. The oxidation system proceeds well in the absence of organic co-solvents and surfactants. The electron-deficient Fe(TDCPP)Cl catalyst could easily be recycled and reused without loss of activity and the oxidant's by-product (n-Bu4NHSO4) could also be recycled. (c) 2011 Elsevier B.V. All rights reserved.

引用

页码：761 / 765

页数：5

共 2 条

[1] Clean and selective oxidation of alcohols with n-Bu4NHSO5 catalyzed by ionic liquid immobilized TEMPO in ionic liquid [bmim][PF6]
Zhu, Chenjie
Ji, Lei
Wei, Yunyang
CATALYSIS COMMUNICATIONS, 2010, 11 (12) : 1017 - 1020
[2] Bu4NHSO4-Catalyzed Direct N-Allylation of Pyrazole and its Derivatives with Allylic Alcohols in Water: A Metal-Free, Recyclable and Sustainable System
Zhuang, Hongfeng
Lu, Nan
Ji, Na
Han, Feng
Miao, Chengxia
ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (24) : 5461 - 5472

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