New heterometallic frameworks with flexible sulfonate-carboxylate ligand: syntheses, structures, and properties

被引：12
|
作者：
Liu, Qing-Yan [1 ]
Li, Li-Qin [1 ]
Wang, Yu-Ling [1 ]
Yang, Er-Ler [1 ]
Wei, Jia-Jia [1 ]
Fu, Jiang-Hong [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China
来源：
CRYSTENGCOMM | 2011年 / 13卷 / 20期
基金：
中国国家自然科学基金;
关键词：
METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; COORDINATION POLYMER; PHOTOPHYSICAL PROPERTIES; PORE SURFACE; COMPLEXES; 4-SULFOBENZOATE; CHEMISTRY; DIVERSITY; SANDWICH;
D O I：
10.1039/c1ce05561e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvothermal reactions of zinc acetate, sodium hydroxide, and sulfosuccinic acid (H3SSC) in alcohol/H2O, afforded two new three-dimensional (3D) heterometallic sulfonate-carboxylate frameworks, namely, [Na2Zn3(mu(3)-OH)(2)(SSC)(2)(H2O)(4)](n) (1) and [Na4Zn(SSC)(2)(H2O)(3.5)](n) (2). Compound 1 contains 2D anionic [Zn-3(mu(3)-OH)(2)(SSC)(2)](2-) layers based on the centrosymmetric mononuclear [Zn(SSC)(2)](4-) units, while compound 2 has 2D anionic [NaZn(SSC)(2)](3-) layers based on the [Zn-2(SSC)(2)] macrocycle units. In both compounds, the 2D anionic layers are linked by sodium ions in various manners to generate quite different 3D architectures. Compounds 1 and 2 exhibit violet photoluminescences in the solid state. In addition, IR spectra, powder X-ray diffraction, elemental analysis, and thermogravimetric analysis of compounds 1 and 2 are also investigated.
引用
收藏
页码：6150 / 6156
页数：7
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