Syntheses and luminescence of three lanthanide complexes constructed by flexible carboxylate ligand

被引:6
|
作者
Yu, X. F. [1 ]
Lu, L. [1 ]
Zhong, Y. R. [1 ]
Luo, W. G. A. [1 ]
Wang, J. [1 ]
机构
[1] Sichuan Univ Sci & Engn, Coll Chem & Environm Engn, Zigong 643000, Peoples R China
关键词
carboxylic acid; supramolecular interaction; photoluminescence; METAL-ORGANIC FRAMEWORKS; THERMAL-STABILITY; CRYSTAL-STRUCTURE; NETWORKS; MOFS;
D O I
10.1134/S1070328417040091
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three new complexes, namely {[Ln(L)(3)(2,2'-Bipy)] (n) center dot H2O} (Ln = Pr (I), Sm (II), and Nd (III)) (HL = 3-(2-hydroxyphenyl)propanoic acid), have been synthesized and structurally characterized. The structural determinations indicated (CIF files CCDC nos. 1472729 (I), 1472730 (II), 1472734 (III)) that I-III have similar dinuclear structures, which can be further linked into 2D sheet via the hydrogen bond interactions. Furthermore, the luminescent properties of I-III show the strong emissive power and feature.
引用
收藏
页码:244 / 251
页数:8
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