Synthesis and characterization of a novel two-dimensional layered vanadate complex containing double helical chains

被引:12
|
作者
Sun, Chunyan [1 ]
Wang, Enbo [1 ]
Xiao, Dongrong [1 ]
An, Haiyan [1 ]
Xu, Lin [1 ]
机构
[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Key Lab Polyoxometale Sci,Minist Educ, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
polyoxovanadate; helical chains; crystal structure;
D O I
10.1016/j.molstruc.2006.11.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel two-dimensional layered vanadate complex 1 [Ni(phen)H2O][V2O6] has been hydrothermally synthesized and characterized by elemental analyses, i.r., x.p.s., t.g. and single crystal X-ray diffraction. The single crystal X-ray diffraction analysis reveals that compound 1 consists of the {V2O6}(n)(2n-) chains covalently linked by [Ni(phen)H2O](2+) subunits to form two-dimensional layered polyoxovanadate. It is interesting that the compound I consists of left-handed and right-handed helical chains, which are further interconnected to produce the double helical chains. The adjacent two-dimensional layers interact with each other via extensive hydrogen bonds and pi-pi stacking interactions to form a three-dimensional supramolecular framework. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:53 / 58
页数:6
相关论文
共 50 条
  • [21] Hydrothermal synthesis and crystal structure of a novel layered vanadate complex containing double helical chains:: [{Zn(2,2′-bpy)}2V8O21](2,2′-bpy=2,2′-bipyridine)
    Xiao, DR
    Hou, Y
    Wang, EB
    Li, YG
    Lü, J
    Xu, L
    Hu, CW
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 691 (1-3) : 123 - 131
  • [22] Polymerlike statistical characterization of two-dimensional granular chains
    Wen, Ping-Ping
    Zheng, Ning
    Li, Liang-Sheng
    Li, Heng
    Sun, Gang
    Shi, Qing-Fan
    PHYSICAL REVIEW E, 2012, 85 (03):
  • [23] Hydrodynamic assembly of two-dimensional layered double hydroxide nanostructures
    Nicholas A. Jose
    Hua Chun Zeng
    Alexei A. Lapkin
    Nature Communications, 9
  • [24] Hydrodynamic assembly of two-dimensional layered double hydroxide nanostructures
    Jose, Nicholas A.
    Zeng, Hua Chun
    Lapkin, Alexei A.
    NATURE COMMUNICATIONS, 2018, 9
  • [25] Two-dimensional lanthanide-isophthalate coordination polymers containing right- and left-handed helical chains
    Zhou, YF
    Jiang, FL
    Xu, Y
    Cao, R
    Hong, MC
    JOURNAL OF MOLECULAR STRUCTURE, 2004, 691 (1-3) : 191 - 195
  • [26] The Structure of Two-dimensional Layered Cu (II) Complex Material
    Tai, Xi-Shi
    ADVANCED RESEARCH ON MATERIAL ENGINEERING, ARCHITECTURAL ENGINEERING AND INFORMATIZATION, 2012, 366 : 392 - 395
  • [27] Synthesis and characterization of a novel Mg/In layered double hydroxide
    Aramendía, MA
    Borau, V
    Jiménez, C
    Marinas, JM
    Romero, FJ
    Urbano, FJ
    JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (10) : 2291 - 2292
  • [28] A comprehensive review of two-dimensional high-entropy layered hydroxides: Synthesis, characterization, and applications
    Hai, Abdul
    Daud, Muhammad
    Mujtaba, Ghulam
    Banat, Fawzi
    Al-Harthi, Mamdouh A.
    COORDINATION CHEMISTRY REVIEWS, 2025, 529
  • [29] Synthesis and Characterization of a Novel Two-Dimensional Network Polymer Containing 18-and 26-Membered Organotin Macrocycles
    Wang, Qingfeng
    Zhang, Jianping
    Han, Yinfeng
    HETEROATOM CHEMISTRY, 2016, 27 (01) : 32 - 36
  • [30] Novel two-dimensional donor-acceptor conjugated polymers containing quinoxaline units: Synthesis, characterization, and photovoltaic properties
    Huo, Lijun
    Tan, Zhan'ao
    Wang, Xiang
    Zhou, Yi
    Han, Minfang
    Li, Yongfang
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (12) : 4038 - 4049