Harvesting 48V at the National Superconducting Cyclotron Laboratory

被引:8
|
作者
Loveless, C. Shaun [1 ,2 ]
Marois, Boone E. [3 ]
Ferran, Samuel J. [1 ]
Wilkinson, John T. [4 ]
Sutherlin, Logan [5 ]
Severin, Gregory [6 ,9 ]
Shusterman, Jennifer A. [7 ]
Scielzo, Nicholas D. [8 ]
Stoyer, Mark A. [8 ]
Morrissey, David J. [9 ]
Robertson, J. David [5 ,6 ]
Peaslee, Graham F. [4 ]
Lapi, Suzanne E. [1 ]
机构
[1] Univ Alabama Birmingham, Dept Radiol, 1720 2nd Ave South,WTI 310F, Birmingham, AL 35233 USA
[2] Washington Univ, Dept Chem, St Louis, MO 63134 USA
[3] Hope Coll, Dept Chem, Holland, MI 49423 USA
[4] Univ Notre Dame, Dept Phys, Notre Dame, IN 46556 USA
[5] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[6] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA
[7] CUNY Hunter Coll, Dept Chem, New York, NY 10065 USA
[8] Lawrence Livermore Natl Lab, Nucl & Chem Sci Div, Livermore, CA 94550 USA
[9] Michigan State Univ, Natl Superconducting Cyclotron Lab, E Lansing, MI 48824 USA
关键词
V-48; Isotope harvesting; Heavy-ion fragmentation; National superconducting cyclotron laboratory; SEPARATION; CHROMIUM; VANADIUM;
D O I
10.1016/j.apradiso.2019.109023
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
As part of an effort to develop aqueous isotope harvesting techniques at radioactive beam facilities, V-48 and a cocktail of primary- and secondary-beam ions created by the fragmentation reaction of a 160 MeV/nucleon Ni-58 beam were stopped in an aqueous target cell. After collection, V-48 was separated from the mixture of beam ions using cation-exchange chromatography. The extraction efficiency from the aqueous solution was (47.0 +/- 2.5)%, and the isolated V-48 had a radiochemical purity of 95.8%. This proof-of-concept work shows that aqueous isotope harvesting could provide significant quantities of rare isotopes which are currently unavailable at conventional facilities.
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页数:7
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