Sandwich "Ion Pool"-Structured Power Gating for Salinity Gradient Generation Devices

Nanoconfinement ion transport, similar to that of biological ion channels, has attracted widespread research interest and offers prospects for broad applications in energy conversion and nanofluidic diodes. At present, various methods were adopted to improve the rectification performance of nanofluidic diodes including geometrical, chemical, and electrostatic asymmetries. However, contributions of the confinement effects within the channels were neglected, which can be a crucial factor for ion rectification behavior. In this research, we report an "ion pool"-structured nanofluidic diode to improve the confinement effect of the system, which was constructed based on an anodic aluminum oxide (AAO) nanoporous membrane sandwiched between zeolitic imidazolate framework 8 (ZIF-8) and tungsten oxide (WO3) thin membranes. A high rectification ratio of 192 is obtained through this nanofluidic system due to ions could be enriched or depleted sufficiently within the ion pool. Furthermore, this high-rectification-ratio ion pool-structured nanofluidic diode possessed pH-responsive and excellent ion selectivity. We developed it as a pH-responsive power gating for a salinity gradient harvesting device by controlling the surface charge density of the ion pool nanochannel narrow ends with different pH values, and hence, the ionic gate is switched between On and Off states, with a gating ratio of up to 27, which exhibited 8 times increase than ZIF-8-AAO and AAO-WO3 composite membranes. Significantly, the peculiar ion pool structure can generate high rectification ratios due to the confinement effect, which then achieves high gating ratios. Such ion pool-structured nanochannels created new avenues to design and optimize nanofluidic diodes and boosted their applications in energy conversion areas.