N-(5-Nitropyridin-2-yl)-5H-dibenzo[d,f][1,3]diazepine-6-carboxamide

被引：4

作者：

Seidler, Tomasz ^{[1
]}

Gryl, Marlena ^{[1
]}

Trzewik, Bartosz ^{[1
]}

Stadnicka, Katarzyna ^{[1
]}

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

D O I：

10.1107/S1600536811018629

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C(19)H(13)N(5)O(3), can be obtained from the corresponding alpha-amido-alpha-aminonitrone in a reaction with biphenyl-2,2'-diamine. The amido-amidine core has distinctive geometrical parameters including: an outstandingly long Csp 2-Csp 2 single bond of 1.5276 (13) A and an amidine N-C-N angle of 130.55 (9)degrees. Intramolecular N-H...O, N-H...N and C-H...O hydrogen bonds occur. In the crystal, molecules form layers parallel to (001) via weak intermolecular C-H...N interactions. The layers are linked via N-H...O hydrogen bonds and pi-pi interactions along [001] [benzene-pyridine centroid-centroid distance = 3.672 (2) A].

引用

页码：O1507 / U1514

页数：13

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