N-(5-Nitropyridin-2-yl)-5H-dibenzo[d,f][1,3]diazepine-6-carboxamide

被引：4
|
作者：
Seidler, Tomasz [1 ]
Gryl, Marlena [1 ]
Trzewik, Bartosz [1 ]
Stadnicka, Katarzyna [1 ]
机构：
[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811018629
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C(19)H(13)N(5)O(3), can be obtained from the corresponding alpha-amido-alpha-aminonitrone in a reaction with biphenyl-2,2'-diamine. The amido-amidine core has distinctive geometrical parameters including: an outstandingly long Csp 2-Csp 2 single bond of 1.5276 (13) A and an amidine N-C-N angle of 130.55 (9)degrees. Intramolecular N-H...O, N-H...N and C-H...O hydrogen bonds occur. In the crystal, molecules form layers parallel to (001) via weak intermolecular C-H...N interactions. The layers are linked via N-H...O hydrogen bonds and pi-pi interactions along [001] [benzene-pyridine centroid-centroid distance = 3.672 (2) A].
引用
收藏
页码：O1507 / U1514
页数：13
相关论文
共 50 条
  • [21] N-(5-Amino-1H-1,2,4-triazol-3-yl)pyridine-2-carboxamide
    Hernandez-Gil, Javier
    Ferrer, Sacramento
    Ballesteros, Rafael
    Castineiras, Alfonso
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O227 - +
  • [22] N-(1H-1,2,4-Triazol-5-yl)pyridine-2-carboxamide
    Miao, Jing
    Jia, Maomao
    Liu, Xianlin
    Xiong, Wei
    Chen, Zilu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2738 - U641
  • [23] N-(3-cyano-1H-indol-5-yl)isonicotinamide and N-(3-cyano-1H-indol-5-yl)-1H-benzo[d]imidazole-5-carboxamide derivatives: Novel amide-based xanthine oxidase inhibitors
    Tu, Shun
    Zhang, Ting-Jian
    Zhang, Yi
    Zhang, Xu
    Zhang, Zhen-Hao
    Meng, Fan-Hao
    BIOORGANIC CHEMISTRY, 2021, 115
  • [24] REDUCTIVE CYCLIZATION OF 2,2'-DINITROBIPHENYL TO 5,7-DIHYDROXY-6H-DIBENZO[D,F][1,3]DIAZEPINES
    BECHER, J
    ACTA CHEMICA SCANDINAVICA, 1972, 26 (04): : 1659 - &
  • [25] N-[3-(5-Oxo-10,11-dihydro-5H-dibenzo[a,d]cyclohepten-2-ylamino)phenyl]furan-3-carboxamide
    Dorn, Angelika
    Schollmeyer, Dieter
    Laufer, Stefan A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1100 - U311
  • [26] Convenient synthesis of N-(2,2-dimethyl-1,3-dioxan-5-yl)-1H-indazole-3-carboxamide, the intermediate of 5-HT3 receptor antagonist
    Morie, T
    Harada, H
    Kato, S
    SYNTHETIC COMMUNICATIONS, 1997, 27 (04) : 559 - 566
  • [27] 3-Bromo-1-(3-chloropyridin-2-yl)-N-(4-ethoxyphenyl)-1H-pyrazole-5-carboxamide
    Yue, Hai
    Dong, Wei-Li
    Wang, Run-Ling
    Cheng, Xian-Chao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2961 - U1463
  • [28] N,N-DIMETHYLSPIRO[5H-DIBENZO[A,D]CYCLOHEPTENE-5,1'-CYCLOHEXANE]-4'-AMINE
    RODGERS, JR
    KENNARD, O
    SHELDRICK, GM
    HORN, AS
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (APR15): : 1293 - 1295
  • [29] Synthesis and Spectral Analysis of 3,4,5-trichloro-6-(dibenzo[d,f][1,3]diazepin-5-yl)-[1,2]-benzoquinones
    Gomaa, Mohsen A. M.
    E-JOURNAL OF CHEMISTRY, 2011, 8 : S91 - S96
  • [30] Design and Syntheses of Novel N-(Benzothiazol-5-yl)-4,5,6,7-tetrahydro-1H-isoindole-1,3(2H)-dione and N-(Benzothiazol-5-yl)isoindoline-1,3-dione as Potent Protoporphyrinogen Oxidase Inhibitors
    Jiang, Li-Li
    Zuo, Yang
    Wang, Zhi-Fang
    Tan, Yin
    Wu, Qiong-You
    Xi, Zhen
    Yang, Guang-Fu
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2011, 59 (11) : 6172 - 6179
12345