N-(5-Nitropyridin-2-yl)-5H-dibenzo[d,f][1,3]diazepine-6-carboxamide

被引：4
|
作者：
Seidler, Tomasz [1 ]
Gryl, Marlena [1 ]
Trzewik, Bartosz [1 ]
Stadnicka, Katarzyna [1 ]
机构：
[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
D O I：
10.1107/S1600536811018629
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C(19)H(13)N(5)O(3), can be obtained from the corresponding alpha-amido-alpha-aminonitrone in a reaction with biphenyl-2,2'-diamine. The amido-amidine core has distinctive geometrical parameters including: an outstandingly long Csp 2-Csp 2 single bond of 1.5276 (13) A and an amidine N-C-N angle of 130.55 (9)degrees. Intramolecular N-H...O, N-H...N and C-H...O hydrogen bonds occur. In the crystal, molecules form layers parallel to (001) via weak intermolecular C-H...N interactions. The layers are linked via N-H...O hydrogen bonds and pi-pi interactions along [001] [benzene-pyridine centroid-centroid distance = 3.672 (2) A].
引用
收藏
页码：O1507 / U1514
页数：13
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