(1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetramethyl-9,10-epoxytricyclo[6.4.0.01,3]dodecane

被引：6

作者：

Benharref, Ahmed ^{[1
]}

El Ammari, Lahcen ^{[2
]}

Avignant, Daniel ^{[3
]}

Oudahmane, Abdelghani ^{[3
]}

Berraho, Moha ^{[1
]}

机构：

[1] Fac Sci, URAC16, Lab Chim Biomol Subst Nat & Reactivite, Marrakech 40000, Morocco

[2] Fac Sci Rabat, Lab Chim Solide Appl, Rabat, Morocco

[3] Univ Blaise Pascal, Lab Mat Inorgan, UMR CNRS 6002, F-63177 Aubiere, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

BETA-HIMACHALENE; EPOXIDATION; OXIDATION; REGIO;

D O I：

10.1107/S1600536810045344

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C16H24Cl2O, was synthesized from beta-himachalene (3,5,5,9-tetramethyl-2,4a, 5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The molecule forms an extended sheet of two fused rings which exhibit different conformations. The six-membered ring has a half-chair conformation, while the seven-membered ring displays a chair conformation; the dihedral angle between the two rings is 38.2 (1)degrees.

引用

页码：O3125 / U220

页数：9

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