(1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetramethyl-9,10-epoxytricyclo[6.4.0.01,3]dodecane

被引：6

作者：

Benharref, Ahmed ^{[1
]}

El Ammari, Lahcen ^{[2
]}

Avignant, Daniel ^{[3
]}

Oudahmane, Abdelghani ^{[3
]}

Berraho, Moha ^{[1
]}

机构：

[1] Fac Sci, URAC16, Lab Chim Biomol Subst Nat & Reactivite, Marrakech 40000, Morocco

[2] Fac Sci Rabat, Lab Chim Solide Appl, Rabat, Morocco

[3] Univ Blaise Pascal, Lab Mat Inorgan, UMR CNRS 6002, F-63177 Aubiere, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

BETA-HIMACHALENE; EPOXIDATION; OXIDATION; REGIO;

D O I：

10.1107/S1600536810045344

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C16H24Cl2O, was synthesized from beta-himachalene (3,5,5,9-tetramethyl-2,4a, 5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The molecule forms an extended sheet of two fused rings which exhibit different conformations. The six-membered ring has a half-chair conformation, while the seven-membered ring displays a chair conformation; the dihedral angle between the two rings is 38.2 (1)degrees.

引用

页码：O3125 / U220

页数：9

共 50 条

[21] (4R,5R,6S,7R,8S,9R,10S,13S)-7,8β-epoxymomilactone-A
Habib, Rana Shabnam
Jamshaid, Muhammad
Tahir, M. Nawaz
Khan, Tahir Javed
Khan, Islam Ullah
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O892 - U2387
[22] (1S,3R,8R)-2,2-Dibromo-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodec-9-en-11-one
Oukhrib, Abdelouahd
Benharref, Ahmed
Saadi, Mohamed
El Ammari, Lahcen
Berraho, Moha
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O3341 - +
[23] Absolute configuration of (1S, 3R, 8R)-10-bromomethyl-2,2-dichloro-3,7,7-tri-methyltricyclo[6.4.0.0(1,3)]dodec-9-ene
Bimoussa, Abdoullah
Auhmani, Aziz
Itto, My Youssef Ait
Daran, Jean-Claude
Auhmani, Abdelwahed
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1692 - +
[24] (1S,3R,6S,7R)-3,7-Dichloro-trans-himachalane
Ourhriss, Najia
Mazoir, Noureddine
Daran, Jean-Claude
Berraho, Moha
Benharref, Ahmed
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : o1497 - o1499
[25] (1S,3S,8R,9S)-3,7,7,10-Tetramethyl-9-[(1S,3S,8R,9S)-3,7,7-trimethyl-10-methylenetricyclo[6,4,0,01,3]dodec-9-yloxy]tricyclo[6,4,0,01,3]dodec-10-ene
Auhmani, A
Kossareva, E
Eljamili, H
Reglier, M
Pierrot, M
Benharref, A
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : O102 - o103
[26] C-13 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF 1R(S),3S(R),8R(S),10S(R)- AND 1S(R),3R(S),8R(S),10S(R)-3,5,7,7,10,12,14,14-OCTAMETHYL-1,4,8,11 TETRAAZACYCLOTETRADECA-4,11-DIENENICKEL(II) COMPLEXES
ITO, T
SOMA, K
WATANABE, M
CHEMISTRY LETTERS, 1976, (05) : 421 - 424
[27] (1S,3R,8R,9S,11R)-2,2-Dibromo-10,10-dichloro-3,7,7,11-tetramethyltetracyclo-[6.5.0.0(1,3).0(9,11)]tridecane
Ourhriss, Najia
Benharref, Ahmed
Saadi, Mohamed
Berraho, Moha
El Ammari, Lahcen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O724 - +
[28] (1S,3S,8R,10R,11R)-3,7,7,10-Tetramethyltricyclo[6.4.0.0(1,3)]dodecan-11-ol
Benharref, Ahmed
El Karroumi, Jamal
El Ammari, Lahcen
Saadi, Mohamed
Berraho, Moha
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1350 - +
[29] Crystal structure of (1R,2S,4R,7R,8S,9R)-3,3-dichloro-8,9-epoxy-4,8,12,12-tetramethyltricyclo[5.5.0.0(2,4)]dodecane
Benzalim, Ahmed
Auhmani, Aziz
Itto, My Youssef Ait
Daran, Jean-Claude
Auhmani, Abdelwahed
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O538 - +
[30] Theoretical study of stereoselectivity of the [1+2] cycloaddition reaction between (1S,3R,8S)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6,4,0,01.3]dodec-9-ene and dibromocarbene using density functional theory (DFT) B3LYP/6-31G*(d)
Zeroual, Abdellah
Benharref, Ahmed
El Hajbi, Abdeslam
JOURNAL OF MOLECULAR MODELING, 2015, 21 (03)

← 1 2 3 4 5 →