(1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetramethyl-9,10-epoxytricyclo[6.4.0.01,3]dodecane

被引：6
|
作者：
Benharref, Ahmed [1 ]
El Ammari, Lahcen [2 ]
Avignant, Daniel [3 ]
Oudahmane, Abdelghani [3 ]
Berraho, Moha [1 ]
机构：
[1] Fac Sci, URAC16, Lab Chim Biomol Subst Nat & Reactivite, Marrakech 40000, Morocco
[2] Fac Sci Rabat, Lab Chim Solide Appl, Rabat, Morocco
[3] Univ Blaise Pascal, Lab Mat Inorgan, UMR CNRS 6002, F-63177 Aubiere, France
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
BETA-HIMACHALENE; EPOXIDATION; OXIDATION; REGIO;
D O I：
10.1107/S1600536810045344
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, C16H24Cl2O, was synthesized from beta-himachalene (3,5,5,9-tetramethyl-2,4a, 5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The molecule forms an extended sheet of two fused rings which exhibit different conformations. The six-membered ring has a half-chair conformation, while the seven-membered ring displays a chair conformation; the dihedral angle between the two rings is 38.2 (1)degrees.
引用
收藏
页码：O3125 / U220
页数：9
相关论文
共 50 条
  • [1] (1S,3R,8S,9S,10R)-2,2-Dichloro-9,10-epoxy-3,7,7,10-tetramethyl-tricyclo[6.4.0.01,3]dodecane and (1S,3R,8S,10R)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.01,3]dodecan-9-one
    Dakir, M
    Auhmani, A
    El Jamili, H
    Akssira, M
    Benharref, A
    Kenz, A
    Pierrot, M
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2002, 58 : o518 - o520
  • [2] (1S,3R,8S,9S,10R)-2,2-Dichloro-9,10-epoxy-3,7,7,10-tetramethyl- tricyclo[6.4.0.01,3]dodecane and (1S,3R,8S,10R)-2,2-dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.01,3]dodecan-9-one (vol C58, pg o518, 2002)
    Dakir, M
    Auhmani, A
    El Jamili, H
    Akssira, M
    Benharref, A
    Kenz, A
    Pierrot, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : E10 - E10
  • [3] (1S,3R,8R,9R,10S)-2,2-Dibromo-3,7,7,10-tetramethyl-9 beta,10 beta-epoxy-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]-dodecane
    Oukhrib, Abdelouahd
    Benharref, Ahmed
    Saadi, Mohamed
    Berraho, Moha
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O521 - +
  • [4] (1S,3R,8R,11S)-2,2-Dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.01,3]dodec-9-en-11-ol
    Benharref, Ahmed
    Lassaba, Essediya
    Avignant, Daniel
    Oudahmane, Abdelghani
    Berraho, Moha
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O615 - U1685
  • [5] (1S, 2R,8R)-2,2-Dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.01,3]dodec-10-en-9-one
    Benharref, Ahmed
    El Ammari, Lahcen
    Berraho, Moha
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2911 - U1012
  • [6] 1S,3R,8R)-9-(1-Aminoethylidene)-2,2-dichloro-3,7,7-trimethyltricyclo[6.4.0.01,3]undecan-10-one
    Benharref, Ahmed
    Lassaba, Essediya
    Avignant, Daniel
    Oudahmane, Abdelghani
    Berraho, Moha
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O645 - U1967
  • [7] Crystal structure of (1S,3R,8R,9R,10S)-2,4,6-tris(2,2-dichloro-3,7,7,10-tetramethyltri-cyclo[6.4.0.0(1,3)]dodec-9-yl)cyclotriboroxane
    Benharref, Ahmed
    El Ammari, Lahcen
    Saadi, Mohamed
    Mazoir, Noureddine
    Berraho, Moha
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 941 - +
  • [8] (1S,3R,8R)-2,2-Dichloro-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodec-9-en-11-one
    Ourhriss, Naja
    Benharref, Ahmed
    Oukhrib, Abdelouahd
    Daran, Jean-Claude
    Berraho, Moha z
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O830 - +
  • [9] Crystal structure of (1S,3R,8R,10S)-2,2-dichloro-10-hydroxy-3,7,7,10-tetramethyltricyclo[6.4.0.0(1,3)]dodecan-9-one
    Benzalim, Ahmed
    Auhmani, Aziz
    Itto, My Youssef Ait
    Daran, Jean-Claude
    Abdelwahed, Auhmani
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 709 - +
  • [10] Crystal structure of (1S,3R,8R,9R)-2,2-dichloro-3,7,7-trimethyl-10-methylenetricyclo[6.4.0.0(1,3)]dodecan-9-ol
    Benzalim, Ahmed
    Auhmani, Aziz
    Bimoussa, Abdoullah
    Itto, My Youssef Ait
    Daran, Jean-Claude
    Auhmani, Abdelwahed
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1163 - +
12345