N-functionalization of the tetrahedrane Fe-2(CO)(6)(mu-SNH)

被引：0
|
作者：
Herberhold, M
Bertholdt, U
Milius, W
Wrackmeyer, B
机构：
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 09期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The azadiferrathia tetrahedrane, Fe-2(CO)(6)(mu-SNH) (1), was deprotonated to give the anion [Fe-2(CO)(6)(mu-SN)](-) (2) which reacts with halides of phosphorus, arsenic, silicon, germanium, tin and boron by formation of element-nitrogen bonds. The new compounds were characterized by their IR, NMR (H-1, B-11, C-13, N-15, Si-29, P-31 Sn-119) and mass spectra. The molecular structure, of [Fe-2(CO)(6)(mu-SN-SiMe(2)CH(2-))](2) (11) was determined by X-ray structure analysis (space group <P(1)over bar>; triclinic; a = 799.8(2), b = 958.5(2), c = 1035.7(2) pm, alpha = 86.30(2)degrees, beta = 81.27(2)degrees, gamma = 69.90(2)degrees).
引用
收藏
页码：1283 / 1289
页数：7
相关论文
共 50 条
  • [11] CRYSTAL STRUCTURE OF Fe-S CLUSTER COMPLEX (mu-MeS) [mu-Fe(CO)(2)CpS] Fe-2(CO)(6)
    Yao Xinkan
    Song Licheng
    Wang Honggen
    Liu Ronggang
    Wang Ruji
    Wang Jitao
    ACTA PHYSICO-CHIMICA SINICA, 1987, 3 (06) : 604 - 608
  • [12] SYNTHESIS AND CHARACTERIZATION OF THE METHYLENE-INSERTED MIXED-CHALCOGENIDE COMPOUNDS FE-2(CO)(6)(MU-SECH2TE) AND FE-2(CO)(6)(MU-SCH2TE)
    MATHUR, P
    MANIMARAN, B
    HOSSAIN, MM
    SHANBAG, R
    MURTHY, J
    SARANATHAN, IS
    SATYANARAYANA, CVV
    BHADBHADE, MM
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 490 (1-2) : 173 - 178
  • [13] REACTIONS OF [FE-2(CO)(6)(MU-CO)(MU-DPPM)], WITH PHC-CH AND THE PHOSPHA-ALKYNE, (T)BUC-P - CRYSTAL AND MOLECULAR-STRUCTURES OF THE 4 DIIRON COMPLEXES [FE-2(CO)(4)(MU-CO)(MU-DPPM)(2)], [FE-2(CO)(5)(MU-DPPM)(MU-ETA(2)-CHC(CO)PH], [FE-2(CO)(4)(MU-CO)(MU-DPPM)(MU-ETA(2)-(T)BUCP)], AND [FE-2(CO)(5)(MU-DPPM)(MU-ETA(2)-PC(CO)(T)BU)]
    HITCHCOCK, PB
    MADDEN, TJ
    NIXON, JF
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 463 (1-2) : 155 - 162
  • [14] Synthesis and spectroscopic characterization of (CO)(6)Fe-2{mu-EC(H)=C(H)E'} (E not equal E'; E,E'=S, Se, Te) and (CO)(6)Fe-2{mu-TeC(H)=C(H)Te}. Structural characterization of (CO)(6)Fe-2{mu-SC(Ph)=C(H)Se} and (CO)(6)Fe-2{mu-SC(H)=C(Ph)Te}
    Mathur, P
    Dash, AK
    Hossain, M
    Umbarkar, SB
    Satyanarayana, CVV
    Chen, YS
    Holt, EM
    Rao, SN
    Soriano, M
    ORGANOMETALLICS, 1996, 15 (05) : 1356 - 1361
  • [15] REACTIONS OF (MU(2)-CARBYNE)(MU-RS)FE-2(CO)(6) COMPLEXES - ISOMERIZATION AND ACETYLENE INSERTION
    SEYFERTH, D
    RUSCHKE, DP
    DAVIS, WM
    ORGANOMETALLICS, 1994, 13 (12) : 4695 - 4703
  • [16] SELECTIVE N-FUNCTIONALIZATION OF 6-SUBSTITUTED-2-PYRIDONES
    LIU, H
    KO, SB
    JOSIEN, H
    CURRAN, DP
    TETRAHEDRON LETTERS, 1995, 36 (49) : 8917 - 8920
  • [17] HEXACARBONYL DIIRON STABILIZED SULFIMIDE DERIVATIVES, FE-2(CO)(6)(MU-SNR)
    HERBERHOLD, M
    BERTHOLDT, U
    MILIUS, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (08): : 1252 - 1256
  • [18] Synthesis, spectroscopic and structural characterisation of {(CO)(3)Fe(mu-CH2)Se}(2) and (CO)(6)Fe-2{mu-Se(CH2)(n)Se} (n=1,2)
    Mathur, P
    Manimaran, B
    Trivedi, R
    Hossain, MM
    Arabatti, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 515 (1-2) : 155 - 162
  • [19] SYNTHESIS AND CRYSTAL-STRUCTURE OF [(CO)(6)FE-2(MU-SECH3)(2)]
    MATHUR, P
    TRIVEDI, R
    HOSSAIN, M
    TAVALE, SS
    PURANIK, VG
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 491 (1-2) : 291 - 294
  • [20] FACILE SYNTHESES AND TRANSFORMATIONS OF A SERIES OF TELLURIUM IRON CARBONYL CLUSTERS - CRYSTAL-STRUCTURES OF [PHCH(2)NME(3)](2)[TE6FE8(CO)(24)], FE-2(CO)(6)(MU-TECHCL2)(2), AND FE-2(CO)(6)(MU-TECHPHTE)
    SHIEH, M
    CHEN, PF
    TSAI, YC
    SHIEH, MH
    PENG, SM
    LEE, GH
    INORGANIC CHEMISTRY, 1995, 34 (08) : 2251 - 2254
12345