REACTIONS OF [FE-2(CO)(6)(MU-CO)(MU-DPPM)], WITH PHC-CH AND THE PHOSPHA-ALKYNE, (T)BUC-P - CRYSTAL AND MOLECULAR-STRUCTURES OF THE 4 DIIRON COMPLEXES [FE-2(CO)(4)(MU-CO)(MU-DPPM)(2)], [FE-2(CO)(5)(MU-DPPM)(MU-ETA(2)-CHC(CO)PH], [FE-2(CO)(4)(MU-CO)(MU-DPPM)(MU-ETA(2)-(T)BUCP)], AND [FE-2(CO)(5)(MU-DPPM)(MU-ETA(2)-PC(CO)(T)BU)]

被引：14

作者：

HITCHCOCK, PB ^{[1
]}

MADDEN, TJ ^{[1
]}

NIXON, JF ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 463卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83413-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkyne and phospha-alkyne complexes [Fe-2(CO)(5)(mu-dppm)(mu-eta(2)-CHC(CO)Ph)], [Fe-2(CO)(4)(mu-CO)(mu-dppm)(mu-eta(2)-(t)BuCP)], and [Fe-2(CO)(5)(mu-dppm)(mu-eta(2)-PC(CO)(t)Bu] have been synthesized. Their structures are discussed together with that of [Fe2CO)(4)(mu-CO)(mu-dppm)(2)]. PC(CO)(t)Bu)]/

引用

页码：155 / 162

页数：8

共 50 条

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MORTON, DAV
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[J]. POLYHEDRON, 1995, 14 (19) : 2723 - 2743
[2] Diiron acetylide complexes: Molecular structures of [Fe2(CO)4(mu-C CPh)(mu-PPh2)(mu-dppm)] and [Fe-2(CO)(3)(Ph2PC CPh)(mu-C CPh)(mu-PPh2)(mu-dppm)]
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 534 (1-2) : 221 - 227
[3] Protonation of the Co-Rh bond in CoRh(mu-CO)(CO)(2)(mu-dppm)(2)
Bo, C
Poblet, JM
Costas, M
Sarasa, JP
[J]. THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE, 1996, 371 : 37 - 43
[4] Diiron sigma-pi alkenyl complexes: Crystals structures of cis-[Fe-2(Co)(4)(mu-RC CH2)(mu-dppm)], (R=Ph, CH2, OH), trans-[Fe-2(CO)(4)(mu-HC=CHPh)(mu-PPh(2))(mu-dppm)] and the alpha,beta-unsaturated acyl complex trans-[Fe-2(CO)(4){mu O=C-C(Ph)=CH2}(mu-PCy(2))(mu-dppm)]
Hogarth, G
Lavender, MH
Shukri, K
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 527 (1-2) : 247 - 258
[5] Reactions of [Pt-2(mu-CO)(CO)(2)(mu-dppm)(2)] with primary silanes and disilanes.
Hennis, A
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[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 159 - INOR
[6] X-RAY CRYSTAL-STRUCTURES OF PPN[FE-2(MU-CO)(CO)(6)(MU-PBU(2)(T))] [PPN=(PPH(3))(2)N+] AND [FE-2(MU-CO)(CO)(6)(MU-H)(MU-PBU(2)(T))] AND STRUCTURAL COMPARISON WITH THE CLUSTER [FE-2(MU-AG(PPH(3)))(MU-CO)(CO)(6)(MU-PBU(2)(T))]
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[J]. POLYHEDRON, 1994, 13 (20) : 2893 - 2897
[7] REACTIONS OF THE A-FRAME COMPLEXES [RH2(MU-OH-CL)(CO)2(MU-DPPM)2]-H2O AND [RH2(MU-X)(CO)2(MU-DPPM)2]CLO4 [RH2(MU-NCO)(CO)2(MU-DPPM)2]CLO4, [RH2(MU-N-3)(CO)2(MU-DDPM)2]CLO4, [RH2(MU-NCS)(CO)2(MU-DPPM)2]CLO4, [RH2(MU-SCN)(CO)2(MU-DPPM)2]CLO4 WITH CO AND SO2 - SYNTHESIS OF A SIGMA-PI-BRIDGING CYANIDE COMPLEX, [RH2(MU-CN)(MU-CO)(CO)2-(MU-DPPM)2]CLO42(
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[J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 84 (02): : 205 - 211
[8] High-pressure synthesis of [Ru-2(mu-dppm)(2)(mu-CO)(CO)(4), Ru-2(mu-dppm)(mu-dmpm)(mu-CO)(CO)(4)], and [Ru(dcypm)(CO)(3)] from Ru-3(CO)(12) and the diphosphines: R(2)PCH(2)PR(2); R=CH3 (dmpm), C6H5 (dppm) and C6H11 (dcypm). Crystal and molecular structures of [Ru-2(mu-dppm)(2) (mu-CO)(CO)(4)], and [Ru(dcypm)(CO)(3)]
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Kubiak, CP
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[J]. POLYHEDRON, 1997, 16 (09) : 1453 - 1459
[9] THE SYSTEMATIC SYNTHESIS OF HETEROBIMETALLIC COMPLEXES WITH ONLY ONE BRIDGING PH2PCH2PPH2 (DPPM) LIGAND - CRYSTAL-STRUCTURES OF [(OC)4FE(MU-DPPM)RHCL(CO)] AND [(OC)3FE(MU-DPPM)(MU-CO)PTBR2]
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SCHREINER, S
GALLAHER, TN
[J]. ORGANOMETALLICS, 1993, 12 (10) : 4201 - 4203

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