Semi-interpenetrating polymer network of poly(methyl methacrylate) and ether-modified polysiloxane

被引：18

作者：

Cznotka, Eva ^{[1
]}

Jeschke, Steffen ^{[1
]}

Vettikuzha, Preeya ^{[1
]}

Wiemhoefer, Hans-Dieter ^{[1
]}

机构：

[1] Univ Munster, Inst Inorgan & Analyt Chem, D-48149 Munster, Germany

来源：

SOLID STATE IONICS | 2015年 / 274卷

关键词：

Solid polymer electrolyte; Lithium-ion battery; FTIR; Semi-IPN; PMMA; Polysiloxane; LITHIUM-ION BATTERIES; INORGANIC HYBRID ELECTROLYTES; CONDUCTIVITY BEHAVIOR; POLY(ETHYLENE OXIDE); GEL ELECTROLYTES; PMMA; BLENDS; FTIR; SPECTROSCOPY; MEMBRANES;

D O I：

10.1016/j.ssi.2015.02.013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solid polymer electrolyte membranes are prepared as semi-interpenetrating networks (semi-IPN) by solution casting technique composed of poly(methyl methacrylate) (PMMA) as polymeric host Matrix, polysiloxane-combpropyloxymethoxytriglycol (PSx) as ion conducting component and lithium bis(trifluoromethane)sulfonimide (LiTFSI) as conducting salt. The resulting semi-IPN (net-poly(methyl methacrylate))-sipn-(polysiloxane-combpropyloxymethoxytriglycol), is investigated using differential scanning calorimetry (DSC), Fourier transform infrared (FTIR) spectroscopy and impedance spectroscopy (IS). DSC measurements show two glass transitions (Tg-PSx, Tg-PMMA) indicating an independent coexistence of the PMMA host matrix and the PSx conducting component. FTIR spectroscopy reveals interactions between Li+ ions and the ether-functionality of PSx, whereas PMMA does not interact with the Li+. In order to distinguish PMMA and PSx contributions to the ionic transport, the effective ionic conductivity of PSx was calculated. The ionic conductivity of the semi-IPN is 3.1 x 10(-6) S cm(-1) at room temperature. (C) 2015 Elsevier BM. All rights reserved.

引用

页码：55 / 63

页数：9

共 50 条

[1] Characterization of semi-interpenetrating polymer electrolytes containing poly(vinylidene fluoride-co-hexafluoropropylene) and ether-modified polysiloxane
Cznotka, Eva
Jeschke, Steffen
Wiemhoefer, Hans-Dieter
SOLID STATE IONICS, 2016, 289 : 35 - 47
[2] THE TRANSPARENCY OF POLYURETHANE POLY(METHYL METHACRYLATE) INTERPENETRATING AND SEMI-INTERPENETRATING POLYMER NETWORKS
JEHL, D
WIDMAIER, JM
MEYER, GC
EUROPEAN POLYMER JOURNAL, 1983, 19 (07) : 597 - 600
[3] Studies on semi-interpenetrating polymer network based on nitrile rubber and poly(methyl methacrylate)
Samui, AB
Dalvi, VG
Patri, M
Chakraborty, BC
Deb, PC
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 91 (01) : 354 - 360
[4] Studies on semi-interpenetrating polymer network based on nitrile rubber and poly(methyl methacrylate)
Deb, P.C. (director@ncml.ernet.in), 1600, John Wiley and Sons Inc. (91):
[5] Acoustical, damping and thermal properties of polyurethane/poly(methyl methacrylate)-based semi-interpenetrating polymer network foams
Moradi, Gholamreza
Nassiri, Parvin
Ershad-Langroudi, Amir
Monazzam, Mohammad Reaz
PLASTICS RUBBER AND COMPOSITES, 2018, 47 (05) : 221 - 231
[6] MORPHOLOGY AND THERMAL BEHAVIOUR OF POLY(METHYL METHACRYLATE)/POLY(ETHYLENE GLYCOL) SEMI-INTERPENETRATING POLYMER NETWORKS
Lin-Jian, Shangguan
Guoqin, Liu
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2011, 56 (04): : 918 - 921
[7] Novel simultaneous semi-interpenetrating polymer network of crosslinked poly(methyl methacrylate) and poly(2-benzyl-2-oxazoline)
J Macromol Sci Pure Appl Chem, 11 (1601):
[8] A novel simultaneous semi-interpenetrating polymer network of crosslinked poly(methyl methacrylate) and poly(2-benzyl-2-oxazoline)
Culbertson, BM
Xue, YP
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1996, A33 (11): : 1601 - 1608
[9] Shape memory polymer system of semi-interpenetrating network structure composed of crosslinked poly (methyl methacrylate) and poly (ethylene oxide)
Ratna, Debdatta
Karger-Kocsis, J.
POLYMER, 2011, 52 (04) : 1063 - 1070
[10] Rheological, mechanical, and morphological studies of Epoxy/Poly(methyl methacrylate) semi-interpenetrating polymer networks
Siddaramaiah
Barcia, Fabio L.
Sirqueira, Alex S.
Paranhos, Caio M.
Soares, Bluma G.
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 106 (06) : 3808 - 3815

← 1 2 3 4 5 →