MORPHOLOGY AND THERMAL BEHAVIOUR OF POLY(METHYL METHACRYLATE)/POLY(ETHYLENE GLYCOL) SEMI-INTERPENETRATING POLYMER NETWORKS

被引:0
|
作者
Lin-Jian, Shangguan [1 ]
Guoqin, Liu [1 ,2 ]
机构
[1] N China Univ Water Conservancy & Elect Power, Sch Mech Engn, Zhengzhou 450011, Peoples R China
[2] Henan Univ Technol, Coll Mat Sci & Engn, Zhengzhou 450001, Peoples R China
来源
关键词
poly (methyl methacrylate); poly (ethylene glycol); semi-IPNs; morphology; thermal behavour; MECHANICAL-PROPERTIES; CONTROLLED-RELEASE; SHAPE-MEMORY; METHACRYLATE); BLENDS; POLYURETHANE; MISCIBILITY; HYDROGEL; URETHANE;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(methyl methacrylate) (PMMA) networks and linear poly(ethylene glycol) (PEG) can form semi-interpenetrating polymer networks (semi-IPNs), i.e. PMMA/PEG semi-IPNs. The morphology and thermal behaviors of PMMA/PEG semi-IPNs was studied by DSC, TEM, Optical Microscopy, and SEM. The results indicated that the content of PEG and the cross-linking density of PMMA networks have an important influence on the phase separation in the PMMA/PEG semi-IPNs. When the content of PEG and cross-linking density is more than 35 and 3.5 wt%, respectively, PMMA/PEG semi-IPNs are a mixture of PEG in the crystalline state with PMMA networks in the amorphous state.
引用
收藏
页码:918 / 921
页数:4
相关论文
共 50 条
  • [1] SEMI-INTERPENETRATING POLYMER NETWORKS OF CHITOSAN AND POLY(ETHYLENE GLYCOL)
    Milosavljevic, Nedeljko B.
    Krusic, Melina T. Kalagasidis
    Filipovic, Jovanka M.
    [J]. HEMIJSKA INDUSTRIJA, 2008, 62 (06) : 345 - 351
  • [2] Morphology and Thermal Behaviour of Poly (methyl methacrylate-co-N-vinyl-2-pyrrolidone)/Poly (ethylene glycol) Semi-interpenetrating Polymer Networks Based on Hydrogen Bonding Interaction
    Liu, Guoqin
    Liu, Ziran
    Zou, Wenjun
    Li, Zhengxin
    Peng, Jin
    Cheng, Wenxi
    Xu, Sankui
    [J]. ACTA CHIMICA SLOVENICA, 2009, 56 (04) : 946 - 952
  • [3] THE TRANSPARENCY OF POLYURETHANE POLY(METHYL METHACRYLATE) INTERPENETRATING AND SEMI-INTERPENETRATING POLYMER NETWORKS
    JEHL, D
    WIDMAIER, JM
    MEYER, GC
    [J]. EUROPEAN POLYMER JOURNAL, 1983, 19 (07) : 597 - 600
  • [4] Physico-mechanical, thermal and morphological behaviour of polyurethane/poly(methyl methacrylate) semi-interpenetrating polymer networks
    Kumar, H
    Kumar, AA
    Siddaramaiah
    [J]. POLYMER DEGRADATION AND STABILITY, 2006, 91 (05) : 1097 - 1104
  • [5] Thermal characteristics of poly(ethylene oxide)/poly(methyl methacrylate) interpenetrating polymer networks
    Kim, SJ
    Lee, CK
    Kim, SI
    [J]. HIGH PERFORMANCE POLYMERS, 2002, 14 (04) : 351 - 362
  • [6] Facile fabrication of polyurethane/poly(methyl methacrylate) semi-interpenetrating polymer networks for enhanced mechanical and thermal properties
    Tiwari, Pragya
    Bhardwaj, Shakshi
    Singh, Shiva
    Maji, Pradip K.
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2024, 35 (08)
  • [7] Miscibility and thermal and dynamic mechanical behaviour of semi-interpenetrating polymer networks based on polyurethane and poly(hydroxyethyl methacrylate)
    Karabanova, LV
    Boiteux, G
    Gain, O
    Seytre, G
    Sergeeva, LM
    Lutsyk, ED
    [J]. POLYMER INTERNATIONAL, 2004, 53 (12) : 2051 - 2058
  • [8] Preparation of semi-interpenetrating polymer networks composed of silk fibroin and poly(ethylene glycol) macromer
    Kweon, HY
    Park, SH
    Ye, JH
    Lee, YW
    Cho, CS
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 80 (10) : 1848 - 1853
  • [9] Semi-interpenetrating polymer networks composed of silk fibroin and poly(ethylene glycol) for wound dressing
    Kweon, HaeYong
    Yeo, Joo-hong
    Lee, Kwang-gill
    Lee, Hyun Chul
    Na, Hee Sam
    Won, Young Ho
    Cho, Chong Su
    [J]. BIOMEDICAL MATERIALS, 2008, 3 (03)
  • [10] Rheological, mechanical, and morphological studies of Epoxy/Poly(methyl methacrylate) semi-interpenetrating polymer networks
    Siddaramaiah
    Barcia, Fabio L.
    Sirqueira, Alex S.
    Paranhos, Caio M.
    Soares, Bluma G.
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 106 (06) : 3808 - 3815