Synthesis of Some 2-Amino-5-substituted-1,3, 4-oxadiazole Derivatives in the Acetic Acid

被引：0
|
作者：
Kumar, Sanjeev [1 ]
机构：
[1] Univ Allahabad, Iswar Saran Degree Coll, Dept Chem, Allahabad 211004, Uttar Pradesh, India
来源：
E-JOURNAL OF CHEMISTRY | 2011年 / 8卷
关键词：
Semicarbazone; 2-Amino-1,3,4-oxadiazoles; Electrooxidation; Controlled potential; Electrolysis; ANTIINFLAMMATORY ACTIVITY; 1,3,4-OXADIAZOLES;
D O I：
10.1155/2011/757381
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An environmentally benign method for the preparation of 2-amino-5-substituted-1,3,4-oxadiazoles (1a-n) at platinum electrode through the electrooxidation of semicarbazone at room temperature is reported. The electrolysis were carried out at controlled potential in acetic acid solvent using lithium perchlorate as supporting electrolyte in an undivided cell assembly. Square shaped plates of platinum were used for working as well as counter electrode and a third electrode saturated calomel electrode was used as a reference electrode for the measurement of potential difference between two electrodes during the electrolysis.
引用
收藏
页码：S448 / S454
页数：7
相关论文
共 50 条
  • [41] HETEROCYCLIC COMPOUNDS TAUTOMERISM .4. 3-PHENYL 5-AMINO 1,2,4-OXADIAZOLE DERIVATIVES
    SELIM, M
    SELIM, M
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1967, (04): : 1219 - &
  • [42] Synthesis of N-substituted derivatives of (5-amino-2-methyl-1H-indol-3-YL)acetic acid
    Maklakov S.A.
    Smushkevich Yu.I.
    Magedov I.V.
    Chemistry of Heterocyclic Compounds, 2002, 38 (5) : 539 - 542
  • [43] 2-AMINO-1,3,4-OXADIAZOLE .22. 5-(ALPHA-N-DIALKYLAMINOALKYL)-2-AMINO-1,3,4-OXADIAZOLE
    GEHLEN, H
    SIMON, B
    JOURNAL FUR PRAKTISCHE CHEMIE, 1968, 38 (1-2): : 107 - &
  • [44] Synthesis and herbicidal activity of 5-dehydroabietyl-1,3,4-oxadiazole derivatives
    Duan, Wen-Gui
    Li, Xing-Ren
    Mo, Qi-Jin
    Huang, Jian-Xin
    Cen, Bo
    Xu, Xue-Tang
    Lei, Fu-Hou
    HOLZFORSCHUNG, 2011, 65 (02) : 191 - 197
  • [45] Synthesis of 2-amino-5-substituted-1,3,4-oxadiazoles using 1,3-dibromo-5,5-dimethylhydantoin as oxidant
    Rivera, Nelo R.
    Balsells, Jaume
    Hansen, Karl B.
    TETRAHEDRON LETTERS, 2006, 47 (28) : 4889 - 4891
  • [46] SYNTHESIS OF "2-HETARYL-5-PHENYL-1,3,4-OXADIAZOLE AND BIS-1,3,4-OXADIAZOLE DERIVATIVES AND THEIR USE AS FLUORESCENT WHITENERS FOR POLYESTER FIBERS
    RANGNEKAR, DW
    PHADKE, RC
    DYES AND PIGMENTS, 1985, 6 (04) : 293 - 302
  • [47] Synthesis and antibacterial activity of some new 2,5-disubstituted-1,3,4-oxadiazole derivatives
    Somani, Rakesh R.
    Shirodkar, Prabhakar Y.
    Kadam, Vilasrao J.
    CHINESE JOURNAL OF CHEMISTRY, 2008, 26 (09) : 1727 - 1731
  • [48] Transformations of acylation products of functionally 4-substituted 2-alkyl(aryl)-5-hydrazino-1,3-oxazoles into 1,3,4-oxadiazole derivatives
    Golovchenko, AV
    Pil'o, SG
    Brovarets, VS
    Chernega, AN
    Drach, BS
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2005, 75 (03) : 425 - 431
  • [49] Transformations of Acylation Products of Functionally 4-Substituted 2-Alkyl(aryl)-5-hydrazino-1,3-oxazoles into 1,3,4-Oxadiazole Derivatives
    A. V. Golovchenko
    S. G. Pil’o
    V. S. Brovarets
    A. N. Chernega
    B. S. Drach
    Russian Journal of General Chemistry, 2005, 75 : 425 - 431
  • [50] Synthesis and Biological Activity of 5-Pyrimidinyl-1,2,4-oxadiazole Derivatives
    Huang, Tonghui
    Tu, Haiyang
    Liu, Ming
    Hou, Changjian
    Zhang, Aidong
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2011, 31 (06) : 891 - 896
12345