A bright tetranuclear iridium(III) complex

被引：35

作者：

Baranoff, Etienne ^{[1
]}

Orselli, Enrico ^{[2
]}

Allouche, Lionel ^{[3
]}

Di Censo, Davide ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Graetzel, Michael ^{[1
]}

Nazeeruddin, Md. Khaja ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland

[2] Solvay SA, B-1120 Brussels, Belgium

[3] Univ Strasbourg, Inst Chim, CNRS, Serv RMN, F-67008 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

关键词：

PHOTOINDUCED HYDROGEN-PRODUCTION; PHOSPHORESCENT EMISSION AIPE; SENSITIZED SOLAR-CELLS; PHOTOPHYSICAL PROPERTIES; LIGHT; DISCRETE; RHODIUM; METALLOMACROCYCLES; PHOTOCHEMISTRY; CONSTRUCTION;

D O I：

10.1039/c0cc05029f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most interesting properties of mononuclear cyclometallated iridium complexes are retained in the tetranuclear assembly.

引用

页码：2799 / 2801

页数：3

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