A bright tetranuclear iridium(III) complex

被引：35
|
作者：
Baranoff, Etienne [1 ]
Orselli, Enrico [2 ]
Allouche, Lionel [3 ]
Di Censo, Davide [1 ]
Scopelliti, Rosario [1 ]
Graetzel, Michael [1 ]
Nazeeruddin, Md. Khaja [1 ]
机构：
[1] Swiss Fed Inst Technol, Inst Chem Sci & Engn, CH-1015 Lausanne, Switzerland
[2] Solvay SA, B-1120 Brussels, Belgium
[3] Univ Strasbourg, Inst Chim, CNRS, Serv RMN, F-67008 Strasbourg, France
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期
关键词：
PHOTOINDUCED HYDROGEN-PRODUCTION; PHOSPHORESCENT EMISSION AIPE; SENSITIZED SOLAR-CELLS; PHOTOPHYSICAL PROPERTIES; LIGHT; DISCRETE; RHODIUM; METALLOMACROCYCLES; PHOTOCHEMISTRY; CONSTRUCTION;
D O I：
10.1039/c0cc05029f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A cyclic tetranuclear cyclometallated iridium(III) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most interesting properties of mononuclear cyclometallated iridium complexes are retained in the tetranuclear assembly.
引用
收藏
页码：2799 / 2801
页数：3
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