Diastereoselective formation of metallaphosphacyclo iridium(III) complexes from phosphoranido iridium(III) complex

被引：20

作者：

Kajiyama, K ^{[1
]}

Nakamoto, A ^{[1
]}

Miyazawa, S ^{[1
]}

Miyamoto, TK ^{[1
]}

机构：

[1] Kitasato Univ, Sch Sci, Dept Chem, Sagamihara, Kanagawa 2288555, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 04期

关键词：

D O I：

10.1246/cl.2003.332

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A phosphoranido iridium(III) complex is prepared by the reaction of Cp*IrCl2(PMe3) with lithium phosphoranide generated from a P-H spirophosphorane bearing two 8-oxy-1-naphthyl groups. The complex is thermally converted into metallaphosphacyclo complexes with diastereoselectivity.

引用

页码：332 / 333

页数：2

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