Diastereoselective formation of metallaphosphacyclo iridium(III) complexes from phosphoranido iridium(III) complex

被引：20
|
作者：
Kajiyama, K [1 ]
Nakamoto, A [1 ]
Miyazawa, S [1 ]
Miyamoto, TK [1 ]
机构：
[1] Kitasato Univ, Sch Sci, Dept Chem, Sagamihara, Kanagawa 2288555, Japan
来源：
CHEMISTRY LETTERS | 2003年 / 32卷 / 04期
关键词：
D O I：
10.1246/cl.2003.332
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A phosphoranido iridium(III) complex is prepared by the reaction of Cp*IrCl2(PMe3) with lithium phosphoranide generated from a P-H spirophosphorane bearing two 8-oxy-1-naphthyl groups. The complex is thermally converted into metallaphosphacyclo complexes with diastereoselectivity.
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收藏
页码：332 / 333
页数：2
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