CRYSTAL STRUCTURE OF A DINUCLEAR NITRIDO-BRIDGED RUTHENIUM COMPLEX WITH PYRIDINE LIGANDS

被引：1

作者：

Chang, Q. W. ^{[1
]}

Yan, C. X. ^{[1
]}

Jiang, J. ^{[1
]}

Ye, Q. S. ^{[1
]}

Yu, J. ^{[1
]}

Chen, J. L. ^{[1
]}

Cui, H. ^{[1
]}

Liu, W. P. ^{[1
]}

机构：

[1] Kunming Inst Precious Met, State Key Lab Adv Technol Comprehens Utilizat Pla, Kunming, Yunnan, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 03期

关键词：

dinuclear; ruthenium complex; nitrido-bridged; pyridine; crystal structure;

D O I：

10.1134/S0022476617030295

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dinuclear nitrido-bridged ruthenium complex with pyridine ligands ([PyH][Ru2N(Py)(4)Cl-6] (1)is synthesized by reacting K-3[Ru2NCl8(H2O)(2)] (2) and excessive pyridine, then crystallized from dilute hydrochloric acid. Its crystal structure is determined by single crystal X-ray diffraction. The complex crystallizes in the form of red block crystals of the monoclinic symmetry and the space group C-2. The nitrido-bridged ruthenium complex has very short Ru-N distances.

引用

页码：624 / 626

页数：3

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