CRYSTAL STRUCTURE OF A DINUCLEAR NITRIDO-BRIDGED RUTHENIUM COMPLEX WITH PYRIDINE LIGANDS

被引：1
|
作者：
Chang, Q. W. [1 ]
Yan, C. X. [1 ]
Jiang, J. [1 ]
Ye, Q. S. [1 ]
Yu, J. [1 ]
Chen, J. L. [1 ]
Cui, H. [1 ]
Liu, W. P. [1 ]
机构：
[1] Kunming Inst Precious Met, State Key Lab Adv Technol Comprehens Utilizat Pla, Kunming, Yunnan, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 58卷 / 03期
关键词：
dinuclear; ruthenium complex; nitrido-bridged; pyridine; crystal structure;
D O I：
10.1134/S0022476617030295
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new dinuclear nitrido-bridged ruthenium complex with pyridine ligands ([PyH][Ru2N(Py)(4)Cl-6] (1)is synthesized by reacting K-3[Ru2NCl8(H2O)(2)] (2) and excessive pyridine, then crystallized from dilute hydrochloric acid. Its crystal structure is determined by single crystal X-ray diffraction. The complex crystallizes in the form of red block crystals of the monoclinic symmetry and the space group C-2. The nitrido-bridged ruthenium complex has very short Ru-N distances.
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收藏
页码：624 / 626
页数：3
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