Electron-rich, Nitrido-bridged Ruthenium Complexes

被引：8
|
作者：
Glueer, Arne [2 ]
Askevold, Bjorn [1 ]
Schluschass, Bastian [2 ]
Heinemann, Frank W. [1 ]
Schneider, Sven [2 ]
机构：
[1] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91058 Erlangen, Germany
[2] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 01期
关键词：
Nitride; Ruthenium; Bridging ligands; Pincer ligand; CRYSTAL-STRUCTURE; TERMINAL NITRIDO; CHEMISTRY; LIGANDS; REACTIVITY; AMMONIA; IRON;
D O I：
10.1002/zaac.201400166
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Terminal Ru-IV nitride [RuN{N(CH2CH2PtBu2)(2)}] (1) and [RuCl{N(CH2CH2PtBu2)(2)}] (2a) form an equilibrium with bridging nitride [{(tBu(2)PCH(2)CH(2))(2)N} Ru(mu-N) RuCl{N(CH2CH2PtBu2)(2)}] (3a). While 3a could only be spectroscopically characterized yet not isolated, the reaction of the divinylamido chloro complex [RuCl{N(CHCHPtBu2)(2)}] (2b) with half an equivalent azide directly gave the analogous bridging nitride [{(tBu(2)PCHCH)(2)N} Ru(mu N) RuCl{N(CHCHPtBu2)(2)}] (3b), which was isolated and fully characterized.
引用
收藏
页码：49 / 51
页数：3
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