Microwave- and ultrasound-assisted Suzuki-Miyaura cross-coupling reactions catalyzed by Pd/PVP

被引：38
|
作者：
de Souza, Andrea Luzia F. [1 ]
da Silva, Lucyane C. [1 ]
Oliveira, Blanca L. [1 ]
Antunes, O. A. C. [1 ]
机构：
[1] Univ Fed Rio de Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, Brazil
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 24期
关键词：
D O I：
10.1016/j.tetlet.2008.04.061
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Suzuki-Miyaura reactions using Pd/PVP as a catalyst source were carried out in water-ethanol solution. Under MW, sonication or thermal condition yields were very similar, from moderate to very good, in a variety of examples. However, TOFs were very different, 750/h under MW, 250/h under sonication, and 28/h under thermal conditions. Studies carried out under sonication showed that the whole system after product extraction can be re-used at least twice without any noticeable loss of yield. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3895 / 3898
页数：4
相关论文
共 50 条
  • [41] Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
    Martin, Ruben
    Buchwald, Stephen L.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (11) : 1461 - 1473
  • [42] Suzuki-miyaura cross-coupling reactions catalyzed by N-heterocyclic carbene palladium complex
    Shi, Ji-Cheng
    Cao, Xin-Hua
    Zheng, Ying
    Jia, Li
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2007, 27 (05) : 666 - 669
  • [43] Suzuki-Miyaura Cross-Coupling Reactions of Unactivated Alkyl Halides Catalyzed by a Nickel Pincer Complex
    Di Franco, Thomas
    Boutin, Nicolas
    Hu, Xile
    [J]. SYNTHESIS-STUTTGART, 2013, 45 (21): : 2949 - 2958
  • [44] Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of potassium aryl- and heteroaryltrifluoroborates
    Molander, GA
    Biolatto, B
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (11): : 4302 - 4314
  • [45] CuI-catalyzed Suzuki-Miyaura and Sonogashira cross-coupling reactions using DABCO as ligand
    Li, Jin-Heng
    Li, Ji-Lan
    Wang, De-Ping
    Pi, Shao-Feng
    Xie, Ye-Xiang
    Zhang, Man-Bo
    Hu, Xi-Chao
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (06): : 2053 - 2057
  • [46] Azidosubstituted arylboronic acids: synthesis and Suzuki-Miyaura cross-coupling reactions
    Sviridov, SI
    Vasi'ev, AA
    Sergovskaya, NL
    Chirskaya, MV
    Shorshnev, SV
    [J]. TETRAHEDRON, 2006, 62 (11) : 2639 - 2647
  • [47] Suzuki-Miyaura Cross-Coupling Reactions of Primary Alkyltrifluoroborates with Aryl Chlorides
    Dreher, Spencer D.
    Lim, Siang-Ee
    Sandrock, Deidre L.
    Molander, Gary A.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2009, 74 (10): : 3626 - 3631
  • [48] Suzuki-Miyaura Cross-Coupling in Acylation Reactions, Scope and Recent Developments
    Blangetti, Marco
    Rosso, Helena
    Prandi, Cristina
    Deagostino, Annamaria
    Venturello, Paolo
    [J]. MOLECULES, 2013, 18 (01) : 1188 - 1213
  • [49] Palladium Supported on Silk Fibroin for Suzuki-Miyaura Cross-Coupling Reactions
    Rizzo, Giorgio
    Albano, Gianluigi
    Lo Presti, Marco
    Milella, Antonella
    Omenetto, Fiorenzo G.
    Farinola, Gianluca M.
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 2020 (45) : 6992 - 6996
  • [50] Chemoselective Synthesis of Arylpyridines through Suzuki-Miyaura Cross-Coupling Reactions
    Perdomo Rivera, Rodisnel
    Ehlers, Peter
    Ohlendorf, Lars
    Torres Rodriguez, Eugenio
    Villinger, Alexander
    Langer, Peter
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (08) : 990 - 1003
12345