C-H Bond Activation of Methanol and Ethanol by a High-Spin FeIVO Biomimetic Complex

被引：80
|
作者：
Donald, William A. [1 ,2 ]
McKenzie, Christine J. [3 ]
O'Hair, Richard A. J. [1 ,2 ]
机构：
[1] Univ Melbourne, Sch Chem, Inst Mol Sci & Biotechnol Bio21, Melbourne, Vic 3010, Australia
[2] Univ Melbourne, ARC Ctr Excellence Free Rad Chem & Biotechnol, Melbourne, Vic 3010, Australia
[3] Univ So Denmark, Dept Chem & Phys, Odense, Denmark
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 36期
基金：
澳大利亚研究理事会;
关键词：
alcohols; biomimetic chemistry; C-H activation; gas-phase reactions; non-heme iron complexes; GAS-PHASE OXIDATION; SPECTROSCOPIC CHARACTERIZATION; OXOIRON(IV) COMPLEX; FE-IV=O; OXO; GENERATION; LIGANDS; HEME;
D O I：
10.1002/anie.201102146
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C-H vs O-H vs C-O bond activation? The non-heme complex [(bpg)Fe IVO]+ activates the αC-H bond of primary alcohols in vacuum through H abstraction by the FeO group in the rate-determining step. Although this effect counteracts any enhancement of reactivity that results from increasing the formal oxidation state of Fe, it increases the reaction selectivity. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8379 / 8383
页数：5
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