C-H Bond Activation of Methanol and Ethanol by a High-Spin FeIVO Biomimetic Complex

被引：80
|
作者：
Donald, William A. [1 ,2 ]
McKenzie, Christine J. [3 ]
O'Hair, Richard A. J. [1 ,2 ]
机构：
[1] Univ Melbourne, Sch Chem, Inst Mol Sci & Biotechnol Bio21, Melbourne, Vic 3010, Australia
[2] Univ Melbourne, ARC Ctr Excellence Free Rad Chem & Biotechnol, Melbourne, Vic 3010, Australia
[3] Univ So Denmark, Dept Chem & Phys, Odense, Denmark
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 36期
基金：
澳大利亚研究理事会;
关键词：
alcohols; biomimetic chemistry; C-H activation; gas-phase reactions; non-heme iron complexes; GAS-PHASE OXIDATION; SPECTROSCOPIC CHARACTERIZATION; OXOIRON(IV) COMPLEX; FE-IV=O; OXO; GENERATION; LIGANDS; HEME;
D O I：
10.1002/anie.201102146
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
C-H vs O-H vs C-O bond activation? The non-heme complex [(bpg)Fe IVO]+ activates the αC-H bond of primary alcohols in vacuum through H abstraction by the FeO group in the rate-determining step. Although this effect counteracts any enhancement of reactivity that results from increasing the formal oxidation state of Fe, it increases the reaction selectivity. © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8379 / 8383
页数：5
相关论文
共 50 条
  • [21] C-H ACTIVATION Going complex for easy C-H activation
    Boerner, Leigh Krietsch
    CHEMICAL & ENGINEERING NEWS, 2020, 98 (09) : 8 - 8
  • [22] Rapid C-H Bond Activation by a Monocopper(III)-Hydroxide Complex
    Donoghue, Patrick J.
    Tehranchi, Jacqui
    Cramer, Christopher J.
    Sarangi, Ritimukta
    Solomon, Edward I.
    Tolman, William B.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (44) : 17602 - 17605
  • [23] Novel intramolecular C-H bond activation in an iridium dppm complex
    Wiley, JS
    Heinekey, DM
    INORGANIC CHEMISTRY, 2002, 41 (19) : 4961 - 4966
  • [24] Unusual thermal C-H bond activation by a tungsten allene complex
    Ng, SHK
    Adams, CS
    Legzdins, P
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (32) : 9380 - 9381
  • [25] C-H Bond Activation by a Mononuclear Nickel(IV)-Nitrate Complex
    Kwon, Yubin M.
    Lee, Yuri
    Schmautz, Anna K.
    Jackson, Timothy A.
    Wang, Dong
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (27) : 12072 - 12080
  • [26] STEREOSELECTIVE INTRAMOLECULAR C-H BOND ACTIVATION IN A DINUCLEAR IRIDIUM COMPLEX
    HEINEKEY, DM
    MICHEL, ST
    SCHULTE, GK
    ORGANOMETALLICS, 1989, 8 (05) : 1241 - 1246
  • [27] Theoretical Study of Methanol C-H and O-H Bond Activation by PtRu Clusters
    Zhao Jun-Feng
    Sun Xiao-Li
    Li Ji-Lai
    Huang Xu-Ri
    ACTA PHYSICO-CHIMICA SINICA, 2015, 31 (06) : 1077 - 1085
  • [28] Catalytic activation of sp3 C-H bonds by high-spin and spin-crossover Co(II) complexes
    Bell-Taylor, Angela
    Goldsmith, Christian
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [29] CARBON-HYDROGEN BOND ACTIVATION THROUGH A BINUCLEAR C-H BOND COMPLEX
    PARK, JW
    MACKENZIE, PB
    SCHAEFER, WP
    GRUBBS, RH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (20) : 6402 - 6404
  • [30] CARBON-HYDROGEN BOND ACTIVATION THROUGH A BINUCLEAR C-H BOND COMPLEX
    PARK, JW
    MACKENZIE, PB
    SCHAEFER, WP
    GRUBBS, RH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 217 - INOR
12345