A tetranuclear complex of palladium(II) with cysteine

被引：16
|
作者：
Chen, XH [1 ]
Zhu, LG
Duan, CY
Liu, YJ
Kostic, NM
机构：
[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270198001012
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, tetrakis(mu-cysteinato-N,S:S)tetrakis]-[chloropalladium(II)]-dimethyl sulfoxide-diethyl ether (1/3/1), [Pd4Cl4(mu-C3H6NO2S)(4)]. 3(CH3)(2)SO. (CH3CH2)(2)O, contains four nearly square-planar units in each of which the palladium(II) ion is bound to two doubly-bridging thiolate anions from two N,S-bidentate cysteinate ligands, the amino group from one of these ligands, and a chloride anion. The two Pd ... Pd distances in the pairs that are not bridged by the thiolate ligands are 3.203(1) and 3.239(1)Angstrom. If there is any covalent bonding across these distances, it must be very weak.
引用
收藏
页码：909 / 911
页数：3
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