A tetranuclear complex of palladium(II) with cysteine

被引：16
|
作者：
Chen, XH [1 ]
Zhu, LG
Duan, CY
Liu, YJ
Kostic, NM
机构：
[1] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Iowa State Univ, Dept Chem, Ames, IA 50011 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270198001012
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, tetrakis(mu-cysteinato-N,S:S)tetrakis]-[chloropalladium(II)]-dimethyl sulfoxide-diethyl ether (1/3/1), [Pd4Cl4(mu-C3H6NO2S)(4)]. 3(CH3)(2)SO. (CH3CH2)(2)O, contains four nearly square-planar units in each of which the palladium(II) ion is bound to two doubly-bridging thiolate anions from two N,S-bidentate cysteinate ligands, the amino group from one of these ligands, and a chloride anion. The two Pd ... Pd distances in the pairs that are not bridged by the thiolate ligands are 3.203(1) and 3.239(1)Angstrom. If there is any covalent bonding across these distances, it must be very weak.
引用
收藏
页码：909 / 911
页数：3
相关论文
共 50 条
  • [31] Reversible Conversion of Tetranuclear, Trinuclear, and Mononuclear Palladium(II) Complexes with D-Penicillaminate
    Yoshinari, Nobuto
    Hirai, Yusuke
    Kawamoto, Tatsuya
    Igashira-Kamiyama, Asako
    Tsuge, Kiyoshi
    Konno, Takumi
    CHEMISTRY LETTERS, 2009, 38 (11) : 1056 - 1057
  • [32] Structure of a biologically active binuclear palladium complex, bis(bis[(μ2-cysteine)(2,2′-dipyridyl)-palladium(II)]) · hexanitrates · novemhydrates
    A. E. Lapshin
    O. V. Magdysyuk
    A. V. Eremin
    A. N. Belyaev
    Glass Physics and Chemistry, 2009, 35 : 511 - 517
  • [33] Structure of a biologically active binuclear palladium complex, bis(bis[(μ2-cysteine)(2,2'-dipyridyl)-palladium(II)]) • hexanitrates • novemhydrates
    Lapshin, A. E.
    Magdysyuk, O. V.
    Eremin, A. V.
    Belyaev, A. N.
    GLASS PHYSICS AND CHEMISTRY, 2009, 35 (05) : 511 - 517
  • [34] Oxidation of ketone by palladium(II) α-hydroxyketone synthesis catalyzed by a bimetallic palladium(II) complex
    El-Qisairi, AK
    Qaseer, HA
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 659 (1-2) : 50 - 55
  • [35] Synthesis of Tetranuclear Palladium(II) Complexes and Their Catalytic Activity for Cross-Coupling Reactions
    Puls, Florian
    Richter, Nils
    Kataeva, Olga
    Knoelker, Hans-Joachim
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (69) : 17576 - 17583
  • [36] Palladium(II) and platinum(II) tetramethyltetrapyridinoporphyrazine complexes: Redox properties and interactions with cysteine and histidine
    Sekota, M
    Nyokong, T
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 1999, 3 (6-7) : 477 - 487
  • [37] Tetranuclear Cu(II) complex with octaazamacrocycle and bridging bicyclic dicarboxylato ligands
    Miodragovic, ZM
    Vuckovic, G
    Leovac, VM
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2001, 66 (09) : 597 - 603
  • [38] Synthesis, crystal structure and magnetic properties of a tetranuclear Copper(II) complex
    Xie Li-Xia
    Wei Mei-Lin
    Sun Qiao-Zhen
    Duan Chun-Ying
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (03) : 484 - 488
  • [39] Formation of a tetranuclear nickel(ii) complex containing an unusual bridging ligand
    A. Yu. Chernyad"ev
    Yu. A. Ustynyuk
    G. G. Aleksandrov
    A. A. Sidorov
    V. M. Novotortsev
    V. N. Ikorskii
    S. E. Nefedov
    I. L. Eremenko
    I. I. Moiseev
    Russian Chemical Bulletin, 2001, 50 : 1336 - 1338
  • [40] The dipyrrolide ligand as a template for the spontaneous formation of a tetranuclear iron(II) complex
    Love, JB
    Salyer, PA
    Bailey, AS
    Wilson, C
    Blake, AJ
    Davies, ES
    Evans, DJ
    CHEMICAL COMMUNICATIONS, 2003, (12) : 1390 - 1391
12345