Palladium-Catalyzed Aminosulfonylation of Aryl Halides

被引：273
|
作者：
Nguyen, Bao [1 ]
Emmett, Edward J. [1 ]
Willis, Michael C. [1 ]
机构：
[1] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 46期
基金：
英国工程与自然科学研究理事会;
关键词：
SULFUR-DIOXIDE COMPLEXES; SYNTHETIC METHODS; CARBONYLATION REACTIONS; TRIOXIDE COMPLEXES; SULPHUR DIOXIDE; SULFINIC ACIDS; TRANSFORMATIONS; DEOXYGENATION; NITRILES; ALKENES;
D O I：
10.1021/ja1081124
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The palladium-catalyzed three-component coupling of aryl iodides, sulfur dioxide, and hydrazines to deliver aryl N-aminosulfonamides is described. The colorless crystalline solid DABCO center dot(SO2)(2) was used as a convenient source of sulfur dioxide. The reaction tolerates significant variation of both the aryl iodide and hydrazine coupling partners.
引用
收藏
页码：16372 / 16373
页数：2
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