Palladium-Catalyzed Aminosulfonylation of Aryl Halides

被引：273

作者：

Nguyen, Bao ^{[1
]}

Emmett, Edward J. ^{[1
]}

Willis, Michael C. ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Dept Chem, Oxford OX1 3TA, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 46期

基金：

英国工程与自然科学研究理事会;

关键词：

SULFUR-DIOXIDE COMPLEXES; SYNTHETIC METHODS; CARBONYLATION REACTIONS; TRIOXIDE COMPLEXES; SULPHUR DIOXIDE; SULFINIC ACIDS; TRANSFORMATIONS; DEOXYGENATION; NITRILES; ALKENES;

D O I：

10.1021/ja1081124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium-catalyzed three-component coupling of aryl iodides, sulfur dioxide, and hydrazines to deliver aryl N-aminosulfonamides is described. The colorless crystalline solid DABCO center dot(SO2)(2) was used as a convenient source of sulfur dioxide. The reaction tolerates significant variation of both the aryl iodide and hydrazine coupling partners.

引用

页码：16372 / 16373

页数：2

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