Synthesis and Structural Characterization of Antimony Polyazides

被引：13
|
作者：
Lyhs, Benjamin [1 ]
Jansen, Georg [1 ]
Blaeser, Dieter [1 ]
Woelper, Christoph [1 ]
Schulz, Stephan [1 ]
机构：
[1] Univ Duisburg Essen, Dept Chem, D-45117 Essen, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 41期
关键词：
anions; antimony; azides; density functional calculations; X-ray diffraction; THEORETICAL CHARACTERIZATION; VIBRATIONAL-SPECTRA; MOLECULAR STRUCTURE; PHOSPHORUS AZIDES; CRYSTAL; HEXACHLOROANTIMONATES(V); HEXAAZIDOPHOSPHATES; TE(N-3)(4); CHEMISTRY; SALTS;
D O I：
10.1002/chem.201102224
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of antimony polyazides and structural characterization of the pentaazidoantimonite [Sb(N3)5]2- dianion, which is without precedent in Group 15 polyazide chemistry, is reported (see scheme). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11394 / 11398
页数：5
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