Dimeric ortho-palladated complex of 2,3-dimethoxybenzaldehyde oxime catalyzed Suzuki-Miyaura cross-coupling reaction under microwave irradiation

被引：27
|
作者：
Hajipour, Abdol-Reza [1 ]
Rafiee, Fatemeh [2 ]
机构：
[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran
[2] Alzahra Univ, Dept Chem, Fac Sci, Tehran, Iran
来源：
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2015年 / 12卷 / 07期
关键词：
ortho-Palladated catalyst; Palladacycle complexes; Oxime; Suzuki reaction; Biaryls; SONOGASHIRA REACTIONS; HECK REACTION; ELECTROPHILES; BROMIDES; LIQUID;
D O I：
10.1007/s13738-014-0579-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The catalytic activity of dimeric [Pd{C6H2(-CH=NOH)-(OMe)(2)-2,3}(A mu-Cl)](2) complex as an efficient, air, and moisture-tolerant catalyst was investigated in Suzuki cross-coupling reactions of various aryl halides. The combination of homogenous metal catalyst, microwave irradiation, and microwave-active polar solvents gave high yields of substituted biaryl products in short reaction times.
引用
收藏
页码：1177 / 1181
页数：5
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