Dimeric ortho-palladated complex of 2,3-dimethoxybenzaldehyde oxime catalyzed Suzuki-Miyaura cross-coupling reaction under microwave irradiation

被引：27

作者：

Hajipour, Abdol-Reza ^{[1
]}

Rafiee, Fatemeh ^{[2
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran

[2] Alzahra Univ, Dept Chem, Fac Sci, Tehran, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2015年 / 12卷 / 07期

关键词：

ortho-Palladated catalyst; Palladacycle complexes; Oxime; Suzuki reaction; Biaryls; SONOGASHIRA REACTIONS; HECK REACTION; ELECTROPHILES; BROMIDES; LIQUID;

D O I：

10.1007/s13738-014-0579-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic activity of dimeric [Pd{C6H2(-CH=NOH)-(OMe)(2)-2,3}(A mu-Cl)](2) complex as an efficient, air, and moisture-tolerant catalyst was investigated in Suzuki cross-coupling reactions of various aryl halides. The combination of homogenous metal catalyst, microwave irradiation, and microwave-active polar solvents gave high yields of substituted biaryl products in short reaction times.

引用

页码：1177 / 1181

页数：5

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