Relationship between dynamical and equilibrium characteristics of glass-forming polymeric liquids

被引:0
|
作者
Mohanty, U [1 ]
CRaig, N
Fourkas, JT
机构
[1] Boston Coll, Eugene F Merkert Chem Ctr, Chestnut Hill, MA 02467 USA
[2] MIT, Res Sci Inst, Cambridge, MA 02139 USA
来源
PHYSICAL REVIEW E | 2001年 / 64卷 / 01期
关键词
D O I
暂无
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
A connection between measurable equilibrium thermodynamic quantities and a nonequilibrium property of supercooled polymeric liquids. namely, the fragility index, is proposed within the framework of a synthesis of generalized configurational entropy models. The theoretical predictions are compared with experimental data on five glass-forming polymers.
引用
收藏
页数:3
相关论文
共 50 条
  • [41] Dynamical heterogeneities in glass-forming materials
    Heuer, A
    Kuebler, SC
    Tracht, U
    Spiess, HW
    Okun, K
    STRUCTURE AND DYNAMICS OF GLASSES AND GLASS FORMERS, 1997, 455 : 105 - 116
  • [42] Configurational entropy of glass-forming liquids
    Berthier, Ludovic
    Ozawa, Misaki
    Scalliet, Camille
    JOURNAL OF CHEMICAL PHYSICS, 2019, 150 (16):
  • [43] Renewal events in glass-forming liquids
    Julian Helfferich
    The European Physical Journal E, 2014, 37
  • [44] A perspective on the fragility of glass-forming liquids
    Alba-Simionesco, Christiane
    Tarjus, Gilles
    JOURNAL OF NON-CRYSTALLINE SOLIDS-X, 2022, 14
  • [45] Renewal events in glass-forming liquids
    Helfferich, Julian
    EUROPEAN PHYSICAL JOURNAL E, 2014, 37 (08): : 1 - 9
  • [46] VISCOUS FLOW IN GLASS-FORMING LIQUIDS
    LAUGHLIN, WT
    UHLMANN, DR
    AMERICAN CERAMIC SOCIETY BULLETIN, 1968, 47 (04): : 402 - &
  • [47] "Inner clocks" of glass-forming liquids
    Peredo-Ortiz, Ricardo
    Medina-Noyola, Magdaleno
    Voigtmann, Thomas
    Elizondo-Aguilera, Luis F.
    JOURNAL OF CHEMICAL PHYSICS, 2022, 156 (24):
  • [48] On correlated heterogeneities of glass-forming liquids
    Bakai, AS
    LOW TEMPERATURE PHYSICS, 2002, 28 (12) : 896 - 906
  • [49] FRAGILITY METRICS IN GLASS-FORMING LIQUIDS
    Mohanty, Udayan
    ADVANCES IN CHEMICAL PHYSICS, VOL 129, 2004, 129 : 71 - 103
  • [50] Numerical determination of the exponents controlling the relationship between time, length, and temperature in glass-forming liquids
    Cammarota, Chiara
    Cavagna, Andrea
    Gradenigo, Giacomo
    Grigera, Tomas S.
    Verrocchio, Paolo
    JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (19):