Relationship between dynamical and equilibrium characteristics of glass-forming polymeric liquids

被引:0
|
作者
Mohanty, U [1 ]
CRaig, N
Fourkas, JT
机构
[1] Boston Coll, Eugene F Merkert Chem Ctr, Chestnut Hill, MA 02467 USA
[2] MIT, Res Sci Inst, Cambridge, MA 02139 USA
来源
PHYSICAL REVIEW E | 2001年 / 64卷 / 01期
关键词
D O I
暂无
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
A connection between measurable equilibrium thermodynamic quantities and a nonequilibrium property of supercooled polymeric liquids. namely, the fragility index, is proposed within the framework of a synthesis of generalized configurational entropy models. The theoretical predictions are compared with experimental data on five glass-forming polymers.
引用
收藏
页数:3
相关论文
共 50 条
  • [21] On the correlation between fragility and stretching in glass-forming liquids
    Niss, Kristine
    Dalle-Ferrier, Cecile
    Tarjus, Gilles
    Alba-Simionesco, Christiane
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (07)
  • [22] Scaling Description of Dynamical Heterogeneity and Avalanches of Relaxation in Glass-Forming Liquids
    Tahaei, Ali
    Biroli, Giulio
    Ozawa, Misaki
    Popovi, Marko
    Wyart, Matthieu
    PHYSICAL REVIEW X, 2023, 13 (03)
  • [23] Thermoviscoelasticity of glass-forming liquids
    Christensen, Tage
    Olsen, Niels Boye
    Journal of Non-Crystalline Solids, 1998, 235-237 : 296 - 301
  • [24] A THEORY OF GLASS-FORMING LIQUIDS
    LACOMBE, RH
    CALLAHAN, JJ
    ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1981, 371 (OCT) : 316 - 317
  • [25] Relation between thermodynamics and kinetics of glass-forming liquids
    Tanaka, H
    PHYSICAL REVIEW LETTERS, 2003, 90 (05)
  • [26] Dynamical rigidity transition in the viscoelastic properties of chalcogenide glass-forming liquids
    Zhu, Weidi
    Lockhart, Mark
    Aitken, Bruce
    Sen, Sabyasachi
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2018, 502 : 244 - 248
  • [27] Relationship between viscous dynamics and the configurational thermal expansion coefficient of glass-forming liquids
    Reis, Raphael M. C. V.
    Mauro, John C.
    Geisinger, Karen L.
    Potuzak, Marcel
    Smedskjaer, Morten M.
    Guo, Xiaoju
    Allan, Douglas C.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (03) : 648 - 651
  • [28] The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids
    Sastry, S
    NATURE, 2001, 409 (6817) : 164 - 167
  • [29] The relationship between fragility, configurational entropy and the potential energy landscape of glass-forming liquids
    Srikanth Sastry
    Nature, 2001, 409 : 164 - 167
  • [30] Does equilibrium polymerization describe the dynamic heterogeneity of glass-forming liquids?
    Douglas, Jack F.
    Dudowicz, Jacek
    Freed, Karl F.
    JOURNAL OF CHEMICAL PHYSICS, 2006, 125 (14):