Iodine-mediated 1,2-aryl migration of primary benzhydryl amines

被引：1
|
作者：
Du, Yangxu
Hou, Jiao
Lu, Qing
Hao, Wei
Yu, Wenquan [1 ]
Chang, Junbiao [1 ]
机构：
[1] Zhengzhou Univ, Green Catalysis Ctr, Zhengzhou 450001, Henan, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2021年 / 45卷 / 35期
基金：
中国国家自然科学基金;
关键词：
OXIDATIVE REARRANGEMENT; MOLECULAR REARRANGEMENT; BECKMANN REARRANGEMENT;
D O I：
10.1039/d1nj02932k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An iodine-mediated 1,2-aryl migration reaction of primary benzhydryl amines under transition metal-free conditions has been achieved. The crude imines generated by this rearrangement reaction can be directly transformed into various aromatic secondary amine derivatives via reduction or addition reactions. This sequential synthetic process is operationally simple and can be successfully conducted on a gram scale.
引用
收藏
页码：16223 / 16226
页数：4
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