Intermolecular coupling of 2-iodoanilides with benzoxazoles: synthesis of N-(2-Benzoxazol-2-ylphenyl)benzamides via C-H activation

被引：9

作者：

Sasmal, Swarnendu ^{[1
]}

Sen, Indira ^{[1
]}

Hall, Roger G. ^{[2
]}

Pal, Sitaram ^{[1
]}

机构：

[1] Syngenta Biosci Pvt Ltd, Santa Monica Works, Ilhas 403110, Goa, India

[2] Muenchwilen AG, Syngenta Crop Protect, CH-4332 Stein, Switzerland

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 11期

关键词：

Benzoxazole; C-H activation; Intermolecular coupling; o-lodoanilides; INTRAMOLECULAR O-ARYLATION; CATALYZED DIRECT ARYLATION; ONE-POT SYNTHESIS; HETEROAROMATIC-COMPOUNDS; COCATALYTIC SYSTEM; CARBOXYLIC-ACIDS; BOND FORMATION; IN-VIVO; WATER; FERMENTATION;

D O I：

10.1016/j.tetlet.2015.01.150

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using CuI/xantphos/Pd(OAc)(2) catalytic system, the intermolecular C-C cross coupling between benzoxazoles and ortho-haloanilides has been developed in moderate to good yields. The procedure tolerates a series of functional groups on benzoxazole, such as ester, chloro, methyl, and methoxy groups. This divergent approach provides access to various N-(2-Benzoxazol-2-ylphenyl)amides. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：1374 / 1377

页数：4

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