Enantioselectivity in odor perception:: Synthesis and olfactory properties of iso-β-bisabolol, a new natural product

被引：18
|
作者：
Braun, NA [1 ]
Meier, M [1 ]
Schmaus, G [1 ]
Hölscher, B [1 ]
Pickenhagen, W [1 ]
机构：
[1] Symrise GmbH & Co KG, Res & Dev, D-37603 Holzminden, Germany
来源：
HELVETICA CHIMICA ACTA | 2003年 / 86卷 / 07期
关键词：
D O I：
10.1002/hlca.200390219
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The odorous trace constituent iso-beta-bisabolol (4) was isolated from East Indian and Western Australian sandalwood oil and synthesized by using the (E/Z)-triene 12 (iso-gamma-bisabolene) as a key intermediate. Only one of four stereoisomeric forms of 4, (6R,7R)-4a, is odor active, having a strong floral, muguet-like, very pleasant scent.
引用
收藏
页码：2698 / 2708
页数：11
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