Enantioselectivity in odor perception:: Synthesis and olfactory properties of iso-β-bisabolol, a new natural product

被引：18

作者：

Braun, NA ^{[1
]}

Meier, M ^{[1
]}

Schmaus, G ^{[1
]}

Hölscher, B ^{[1
]}

Pickenhagen, W ^{[1
]}

机构：

[1] Symrise GmbH & Co KG, Res & Dev, D-37603 Holzminden, Germany

来源：

HELVETICA CHIMICA ACTA | 2003年 / 86卷 / 07期

关键词：

D O I：

10.1002/hlca.200390219

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The odorous trace constituent iso-beta-bisabolol (4) was isolated from East Indian and Western Australian sandalwood oil and synthesized by using the (E/Z)-triene 12 (iso-gamma-bisabolene) as a key intermediate. Only one of four stereoisomeric forms of 4, (6R,7R)-4a, is odor active, having a strong floral, muguet-like, very pleasant scent.

引用

页码：2698 / 2708

页数：11

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