DeNOx of Nano-Catalyst of Selective Catalytic Reduction Using Active Carbon Loading MnOx-Cu at Low Temperature

被引:11
|
作者
Zhu, Tao [1 ,2 ]
Zhang, Xing [1 ]
Bian, Wenjing [1 ]
Han, Yiwei [1 ]
Liu, Tongshen [3 ]
Liu, Haibing [4 ]
机构
[1] China Univ Min & Technol Beijing, Inst Atmospher Environm Management & Pollut Contr, Beijing 100083, Peoples R China
[2] Shaanxi Key Lab Lacustrine Shale Gas Accumulat &, Xian 710065, Shaanxi, Peoples R China
[3] Beijing Municipal Res Inst Environm Protect, Beijing 100037, Peoples R China
[4] China Minist Ecol Environm, Solid Waste Management Ctr, Beijing 100029, Peoples R China
关键词
low-temperature SCR; activated carbon; nano-catalyst; reaction condition; NO conversion; EFFICIENT CATALYST; OXIDE CATALYSTS; MIXED OXIDES; NOX REMOVAL; CALCINATION TEMPERATURE; NH3-SCR REACTION; NH3; SCR; PROMOTION; MANGANESE;
D O I
10.3390/catal10010135
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With the improvement of environmental protection standards, selective catalytic reduction (SCR) has become the mainstream technology of flue gas deNO(x). Especially, the low-temperature SCR nano-catalyst has attracted more and more attention at home and abroad because of its potential performance and economy in industrial applications. In this paper, low-temperature SCR catalysts were prepared using the activated carbon loading MnOx-Cu. Then, the catalysts were packed into the fiedbed stainless steel micro-reactor to evaluate the selective catalytic reduction of NO performance. The influence of reaction conditions was investigated on the catalytic reaction, including the MnOx-Cu loading amount, calcination and reaction temperature, etc. The experimental results indicate that SCR catalysts show the highest catalytic activity for NO conversion when the calcination temperature is 350 degrees C, MnOx loading amount is 5%, Cu loading amount is 3%, and reaction temperature is 200 degrees C. Under such conditions, the NO conversion arrives at 96.82% and the selectivity to N-2 is almost 99%. It is of great significance to investigate the influence of reaction conditions in order to provide references for industrial application.
引用
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页数:17
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