Nano-MnOx catalyst for the selective catalytic reduction of NO by NH3 in low-temperature

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作者
Tang, Xiao-Long
Hao, Ji-Ming
Xu, Wen-Guo
Li, Jun-Hua
机构
[1] Institute for Chemical Physics, Beijing Institute of Technology, Beijing 100081, China
[2] Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China
来源
Huanjing Kexue/Environmental Science | 2007年 / 28卷 / 02期
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摘要
Nanometer particles composed of manganese oxides (nano-MnOx), which prepared by rheological phase reaction method, show superior low-temperature SCR activity for NO with NH3 in the presence of excess O2. In experiments, the NO conversion is 98.25% at 80°C, and nearly 100% NO could be converted in 100-150°C. Due to the reason of competing adsorption, H2O has a slight impact on the activity and the deactivation of SO2 is reversible. The experiments implied that the superior low-temperature catalytic activity of nano-MnOx was mainly due to its high BET specific areas and poor crystallinity.
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页码:289 / 294
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