Microwave-assisted synthesis of thioamides with elemental sulfur

被引：10

作者：

Milen, Matyas ^{[1
,2
]}

Abranyi-Balogh, Peter ^{[1
]}

Dancso, Andras ^{[2
]}

Keglevich, Gyorgy ^{[1
]}

机构：

[1] Budapest Univ Technol & Econ, Dept Organ Chem & Technol, H-1521 Budapest, Hungary

[2] EGIS Pharmaceut Plc, Div Chem Res, H-1475 Budapest, Hungary

来源：

JOURNAL OF SULFUR CHEMISTRY | 2012年 / 33卷 / 01期

关键词：

benzylamines; thionation; thioamides; fused piperidine derivatives; microwave irradiation; WILLGERODT-KINDLER REACTION; HYDROGEN-SULFIDE; DIPHENYLPHOSPHINODITHIOIC ACID; SODIUM TRIMETHYLSILANETHIOLATE; INTRAMOLECULAR CYCLIZATION; PHOSPHORUS PENTASULFIDE; ORGANIC-REACTIONS; NITRILES; CONVERSION; DERIVATIVES;

D O I：

10.1080/17415993.2011.640329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thioamides are prepared in moderate-to-good yields from the benzylamines or benzylamine derivatives by treatment with elemental sulfur under microwave and solvent-free conditions at 170 degrees C in 15 min. [GRAPHICS] .

引用

页码：33 / 41

页数：9

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