Conjugated polymer-based fluorescence turn-on sensor for nitric oxide

被引：103
|
作者：
Smith, RC [1 ]
Tennyson, AG [1 ]
Lim, MH [1 ]
Lippard, SJ [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 16期
关键词：
D O I：
10.1021/ol0513903
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A turn-on fluorescent sensor for NO (g) in solution was synthesized using a bipyridyl-substituted poly(p-phenylene vinylene) derivative (CP1) as the sensory scaffold. The action of NO (g) upon the CP1-Cu(II) complex reduces it to the CP1-Cu(l) complex with a concomitant 2.8-fold increase in emission intensity. The reagent is selective for NO (g) versus other biological reactive nitrogen species, except for nitroxyl, and has a detection sensitivity limit of 6.3 nM.
引用
收藏
页码：3573 / 3575
页数：3
相关论文
共 50 条
  • [31] Assembled magnetic nanoparticles for photosensitive nitric oxide release and turn-on fluorescence detection in situ
    Jiang, Yubo
    Zhang, Wensheng
    Huang, Shaojun
    Gui, Rijun
    MATERIALS CHEMISTRY AND PHYSICS, 2015, 167 : 231 - 235
  • [32] A real-time fluorescence turn-on assay for trypsin based on a conjugated polyelectrolyte
    Liu, Renxuan
    Tan, Ying
    Zhang, Cunlong
    Wu, Jiatao
    Mei, Lin
    Jiang, Yuyang
    Tan, Chunyan
    JOURNAL OF MATERIALS CHEMISTRY B, 2013, 1 (10) : 1402 - 1405
  • [33] Turn-on conjugated polymer fluorescent chemosensor for fluoride ion
    Tong, H
    Wang, LX
    Jing, XB
    Wang, FS
    MACROMOLECULES, 2003, 36 (08) : 2584 - 2586
  • [34] Turn-on detection of pesticides via reversible fluorescence enhancement of conjugated polymer nanoparticles and thin films
    Talbert, William
    Jones, Daniel
    Morimoto, Joshua
    Levine, Mindy
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (09) : 7273 - 7277
  • [35] Tetraphenylethylene-based Glycoconjugate as a Fluorescence "Turn-On" Sensor for Cholera Toxin
    Hu, Xin-Ming
    Chen, Qi
    Wang, Jin-Xiang
    Cheng, Qian-Yi
    Yan, Chao-Guo
    Cao, Jie
    He, Yu-Jian
    Han, Bao-Hang
    CHEMISTRY-AN ASIAN JOURNAL, 2011, 6 (09) : 2376 - 2381
  • [36] Turn-on fluorescence sensor based on naphthalene anhydride for Hg2+
    Zhong, Zhimin
    Zhang, Dongdong
    Li, Dongmei
    Zheng, Gengxiu
    Tian, Zhongzhen
    TETRAHEDRON, 2016, 72 (49) : 8050 - 8054
  • [37] A Fluorescence Turn-on Sensor for Cyanide Anion Based on Exciplex Signaling Mechanism
    Zhou, Xianshu
    Yang, Hengquan
    Hao, Junsheng
    Yin, Caixia
    Liu, Diansheng
    Guo, Wei
    CHEMISTRY LETTERS, 2012, 41 (05) : 518 - 520
  • [38] A supramolecule based fluorescence turn-on and ratiometric sensor for ATP in aqueous solution
    Singh, Vidya R.
    Singh, Prabhat K.
    JOURNAL OF MATERIALS CHEMISTRY B, 2020, 8 (06) : 1182 - 1190
  • [39] Metal-based turn-on fluorescent probes for sensing nitric oxide
    Lim, Mi Hee
    Lippard, Stephen J.
    ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (01) : 41 - 51
  • [40] Fluorescence Turn-On Sensor for Cyanide Based on a Cobalt(II)-Coumarinylsalen Complex
    Lee, Jae Han
    Jeong, A. Reum
    Shin, Ik-Soo
    Kim, Hae-Jo
    Hong, Jong-In
    ORGANIC LETTERS, 2010, 12 (04) : 764 - 767
12345