Metal-based turn-on fluorescent probes for sensing nitric oxide

被引：225
|
作者：
Lim, Mi Hee [1 ]
Lippard, Stephen J. [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2007年 / 40卷 / 01期
关键词：
D O I：
10.1021/ar950149t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nitric oxide, a reactive free radical, regulates a variety of biological processes. The absence of tools to detect NO directly, rapidly, specifically, and selectively motivated us to synthesize metal-based fluorescent probes to visualize the presence of NO. We prepared and investigated Co(II), Fe( II), Ru(II), Rh( II), and Cu(II) complexes as turn-on fluorescent NO sensors. Our exploration has provided insight into how the interaction of transition-metal centers with nitric oxide can be utilized for NO sensing.
引用
收藏
页码：41 / 51
页数：11
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