Join Si-ZnAs2 of the ternary system Zn-Si-As

被引：4

作者：

Fedorchenko, I. V. ^{[1
]}

Kupriyanova, T. A. ^{[1
]}

Marenkin, S. F. ^{[1
]}

Kochura, A. V. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

Arsenic; Differential Thermal Analysis; Ternary System; Chalcopyrite; Component Solubility;

D O I：

10.1134/S0036023608070267

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The quasi-binary join Si-ZnAs2 of the system Zn-Si-As was studied by physicochemical methods. The congruently melting compound ZnSiAs2 and eutectics Si + ZnSiAs2 and ZnSiAs2 + ZnAs2 are formed along this join. The composition of the eutectic Si + ZnSiAs2 is 90 mol % ZnAs2 and 10 mol % Si; T (m) = 630 degrees C. The composition of the eutectic ZnSiAs2 + Si is 55 mol % Si and 45 mol % ZnAs2. The component solubilities in ZnSiAs2 do not exceed 1 mol %.

引用

页码：1139 / 1143

页数：5

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