Join Si-ZnAs2 of the ternary system Zn-Si-As

被引：4
|
作者：
Fedorchenko, I. V. [1 ]
Kupriyanova, T. A. [1 ]
Marenkin, S. F. [1 ]
Kochura, A. V. [1 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 53卷 / 07期
基金：
俄罗斯基础研究基金会;
关键词：
Arsenic; Differential Thermal Analysis; Ternary System; Chalcopyrite; Component Solubility;
D O I：
10.1134/S0036023608070267
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The quasi-binary join Si-ZnAs2 of the system Zn-Si-As was studied by physicochemical methods. The congruently melting compound ZnSiAs2 and eutectics Si + ZnSiAs2 and ZnSiAs2 + ZnAs2 are formed along this join. The composition of the eutectic Si + ZnSiAs2 is 90 mol % ZnAs2 and 10 mol % Si; T (m) = 630 degrees C. The composition of the eutectic ZnSiAs2 + Si is 55 mol % Si and 45 mol % ZnAs2. The component solubilities in ZnSiAs2 do not exceed 1 mol %.
引用
收藏
页码：1139 / 1143
页数：5
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